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- W2000906077 abstract "Abstract A theoretical study of the phase diagram of ionomer solutions in water is presented. These systems show two phase transitions: a demixing transition and a gelation. The demixing transition is studied using Flory's theory of polymer solutions. The gelation concentration always scales as the overlap concentration c∗ ; the dependence of the phase boundaries on temperature and on the fraction f of metallic groups along the chain is studied. At high temperatures, in a good solvent regime, cgel is proportional to f -8 5 ; at lower temperatures cgel is proportional to f−1." @default.
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- W2000906077 date "1980-01-01" @default.
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- W2000906077 title "Gel formation in ionomers" @default.
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- W2000906077 doi "https://doi.org/10.1016/0032-3861(80)90169-x" @default.
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