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- W2000907965 abstract "The barrier to internal rotation around the phenyl–carbonyl bond in a series of stable protonated p-substituted acetophenones has been determined by means of low temperature 13C NMR and total bandshape analysis resulting in a value of ΔG = 48.1 kJ mol−1 for the unsubstituted protonated compound. The energy results and the 13C chemical shifts are in good agreement with the quasi-planarity of the ground state in p-substituted protonated acetophenones. The barrier heights are discussed in terms of contributions from steric and resonance effects." @default.
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- W2000907965 title "The torsional barrier in aromatic carbonyl compounds. V. Carbon-13 DNMR study of stable protonatedp-substituted acetophenones" @default.
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- W2000907965 doi "https://doi.org/10.1002/mrc.1270110904" @default.
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