FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000910202> ?p ?o ?g. }

• W2000910202 endingPage "340" @default.
• W2000910202 startingPage "331" @default.
• W2000910202 abstract "Vapor-phase epoxidation of propene using H2 and O2 over homogeneously dispersed gold particles deposited by a deposition–precipitation (DP) method on the supports Ti–MCM-41 (hexagonal) and Ti–MCM-48 (cubic) is studied at a space velocity of 4000 h−1·cm−3/g(cat.) and at reaction temperature of 100 or 150°C. Influences of the various parameters investigated in the case of Ti–MCM-48 support are Si/Ti (30, 50, 75, and 100) ratios, precipitating agents (LiOH, NaOH, KOH, RbOH, or CsOH) for Au deposition, pH (6–8), Au loading (2–25 wt% in solution), and calcination temperature (150–500°C). The supports were characterized by XRD, UV–vis, FT-IR, and surface area measurements, whereas supported gold catalysts were characterized by TEM, ICP, and XPS techniques. Better performance was observed with Ti–MCM-48 (initial conversion = 5.6%, PO selectivity = 92%), due to its three-dimensional pore system, than with Ti–MCM-41 (initial conversion = 5.1%, PO selectivity = 88%) in the propene epoxidation at 150°C. GC–MS investigation of the extracted species using organic solvent from the used catalyst revealed that acidic as well as oligomeric species accumulated on the catalyst surfaces. These species are assumed to cause the catalyst deactivation. Silylation of the catalyst Au/Ti–MCM-48 prohibits it from getting deactivated faster and also helps to improve PO selectivity and decrease H2 consumption. Based on the above experimental results, a probable reaction mechanism is explained." @default.
• W2000910202 created "2016-06-24" @default.
• W2000910202 creator A5041762739 @default.
• W2000910202 creator A5047808675 @default.
• W2000910202 creator A5057352872 @default.
• W2000910202 creator A5063162835 @default.
• W2000910202 date "2002-07-01" @default.
• W2000910202 modified "2023-09-25" @default.
• W2000910202 title "Vapor-Phase Epoxidation of Propene Using H2 and O2 over Au/Ti–MCM-48" @default.
• W2000910202 cites W14585249 @default.
• W2000910202 cites W1516895258 @default.
• W2000910202 cites W1580377471 @default.
• W2000910202 cites W1734743771 @default.
• W2000910202 cites W1972222363 @default.
• W2000910202 cites W1982784029 @default.
• W2000910202 cites W1997693922 @default.
• W2000910202 cites W2008328099 @default.
• W2000910202 cites W2010165636 @default.
• W2000910202 cites W2016715357 @default.
• W2000910202 cites W2021464904 @default.
• W2000910202 cites W2029195409 @default.
• W2000910202 cites W2029456521 @default.
• W2000910202 cites W2031087775 @default.
• W2000910202 cites W2033455879 @default.
• W2000910202 cites W2035558906 @default.
• W2000910202 cites W2042602209 @default.
• W2000910202 cites W2046795439 @default.
• W2000910202 cites W2060645496 @default.
• W2000910202 cites W2061491218 @default.
• W2000910202 cites W2062997937 @default.
• W2000910202 cites W2070247802 @default.
• W2000910202 cites W2085197834 @default.
• W2000910202 cites W2092722352 @default.
• W2000910202 cites W2093984797 @default.
• W2000910202 cites W2108753031 @default.
• W2000910202 cites W2140026338 @default.
• W2000910202 cites W2951972164 @default.
• W2000910202 cites W2952987690 @default.
• W2000910202 cites W2998492726 @default.
• W2000910202 cites W3012337170 @default.
• W2000910202 cites W4253827034 @default.
• W2000910202 cites W4255919450 @default.
• W2000910202 doi "https://doi.org/10.1006/jcat.2002.3642" @default.
• W2000910202 hasPublicationYear "2002" @default.
• W2000910202 type Work @default.
• W2000910202 sameAs 2000910202 @default.
• W2000910202 citedByCount "207" @default.
• W2000910202 countsByYear W20009102022012 @default.
• W2000910202 countsByYear W20009102022013 @default.
• W2000910202 countsByYear W20009102022014 @default.
• W2000910202 countsByYear W20009102022015 @default.
• W2000910202 countsByYear W20009102022016 @default.
• W2000910202 countsByYear W20009102022017 @default.
• W2000910202 countsByYear W20009102022018 @default.
• W2000910202 countsByYear W20009102022019 @default.
• W2000910202 countsByYear W20009102022020 @default.
• W2000910202 countsByYear W20009102022021 @default.
• W2000910202 countsByYear W20009102022022 @default.
• W2000910202 countsByYear W20009102022023 @default.
• W2000910202 crossrefType "journal-article" @default.
• W2000910202 hasAuthorship W2000910202A5041762739 @default.
• W2000910202 hasAuthorship W2000910202A5047808675 @default.
• W2000910202 hasAuthorship W2000910202A5057352872 @default.
• W2000910202 hasAuthorship W2000910202A5063162835 @default.
• W2000910202 hasConcept C107054158 @default.
• W2000910202 hasConcept C118792377 @default.
• W2000910202 hasConcept C121332964 @default.
• W2000910202 hasConcept C127413603 @default.
• W2000910202 hasConcept C13965031 @default.
• W2000910202 hasConcept C153294291 @default.
• W2000910202 hasConcept C161790260 @default.
• W2000910202 hasConcept C175583648 @default.
• W2000910202 hasConcept C175708663 @default.
• W2000910202 hasConcept C178790620 @default.
• W2000910202 hasConcept C179104552 @default.
• W2000910202 hasConcept C185592680 @default.
• W2000910202 hasConcept C2777954637 @default.
• W2000910202 hasConcept C2780471494 @default.
• W2000910202 hasConcept C42360764 @default.
• W2000910202 hasConcept C42922719 @default.
• W2000910202 hasConcept C44280652 @default.
• W2000910202 hasConcept C7082614 @default.
• W2000910202 hasConceptScore W2000910202C107054158 @default.
• W2000910202 hasConceptScore W2000910202C118792377 @default.
• W2000910202 hasConceptScore W2000910202C121332964 @default.
• W2000910202 hasConceptScore W2000910202C127413603 @default.
• W2000910202 hasConceptScore W2000910202C13965031 @default.
• W2000910202 hasConceptScore W2000910202C153294291 @default.
• W2000910202 hasConceptScore W2000910202C161790260 @default.
• W2000910202 hasConceptScore W2000910202C175583648 @default.
• W2000910202 hasConceptScore W2000910202C175708663 @default.
• W2000910202 hasConceptScore W2000910202C178790620 @default.
• W2000910202 hasConceptScore W2000910202C179104552 @default.
• W2000910202 hasConceptScore W2000910202C185592680 @default.
• W2000910202 hasConceptScore W2000910202C2777954637 @default.
• W2000910202 hasConceptScore W2000910202C2780471494 @default.
• W2000910202 hasConceptScore W2000910202C42360764 @default.
• W2000910202 hasConceptScore W2000910202C42922719 @default.

• next