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- W2000910689 abstract "The reversed-phase chromatographic behavior of planar and non-planar polycyclic aromatic hydrocarbons (PAHs) is investigated on tetraphenylporphyrin and two metallotetraphenylporphyrin [Sn(IV), In(III)] bonded stationary phases using methanol-water and acetonitrile-water as mixed solvent mobile phases. Large differences in the capacity factors of aromatic solute pairs having the same number of carbon atoms, but differing in three-dimensional shape (e.g., triphenylene/o-terphenyl and perylene/alpha, alpha'-binaphthyl), suggest that the three tetraphenylporphyrin-based supports possess shape selectivity toward small planar aromatic solutes. Capacity factors for planar PAH solutes on these supports are significantly greater than for non-planar polyaryls having the same number of carbon atoms." @default.
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- W2000910689 title "Shape-selective separation of polycyclic aromatic hydrocarbons by reversed-phase liquid chromatography on tetraphenylporphyrin-based stationary phases" @default.
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- W2000910689 doi "https://doi.org/10.1016/0021-9673(93)83457-4" @default.
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