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• W2000916500 abstract "To determine the enantioselectivity of (S)-2,3-di-O-geranylgeranylglyceryl phosphate synthase (DGGGPS) from the thermoacidophilic archaeon Sulfolobus solfataricus, we developed an efficient enantioselective route to the enantiomeric geranylgeranylglyceryl phosphates (R)-GGGP and (S)-GGGP. Previous routes to these substrates involved enzymatic conversions due to the lability of the polyprenyl chains toward common phosphorylation reaction conditions. The synthesis described herein employs a mild trimethyl phosphite/carbon tetrabromide oxidative phosphorylation to circumvent this problem. In contrast to previous results suggesting that only (S)-GGGP can act as the prenyl acceptor substrate, both (R)-GGGP and (S)-GGGP were found to be substrates for DGGGPS." @default.
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• W2000916500 date "2006-01-28" @default.
• W2000916500 modified "2023-09-23" @default.
• W2000916500 title "Total Synthesis of Geranylgeranylglyceryl Phosphate Enantiomers: Substrates for Characterization of 2,3-<i>O</i>-Digeranylgeranylglyceryl Phosphate Synthase" @default.
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• W2000916500 doi "https://doi.org/10.1021/ol0530878" @default.
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