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- W2000923205 abstract "Abstract The complexes [Cd(en)3](SCN)2, [Cd(deen)2(NCS)2], [Cd2(tn)4(NCS)2](SCN)2 and [Cd2(dmtn)4(NCS)2](SCN)2 (where en = 1,2-ethanediamine, deen = N,N-diethyl-1,2-ethanediamine, tn = 1,3-propanediamine and dmtn = N,N-dimethyl-1,3-propanediamine) have been synthesized and their thermal studies carried out. [Cd2(tn)4(NCS)2](SCN)2 undergoes a phase transition (115–130°C; ΔH = 11.8 kJ mol−1) and reverts to the original species (120–90°C; ΔH = −12.4 kJ mol−1) upon cooling. [Cd2(tn)3(NCS)4] has been synthesized from the latter complex in the solid state by the temperature arrest technique, where one of the ligands is found to be bridged. Probable mechanistic paths for the phase transition and decomposition reactions have been proposed." @default.
- W2000923205 created "2016-06-24" @default.
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- W2000923205 date "1985-09-01" @default.
- W2000923205 modified "2023-09-23" @default.
- W2000923205 title "Thermally induced decomposition and phase transition of diamine complexes of cadmium(II) thiocyanate" @default.
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- W2000923205 doi "https://doi.org/10.1016/0040-6031(85)85211-4" @default.
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