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- W2000925564 abstract "[reaction: see text]. Chiral dirhodium(II) complexes, Rh2(O2CCF3)2(PC)2, [PCH = (p-CH3C6H4)3P, (m-CH3C6H4)3P], provide an excellent yield and a high enantiocontrol in the cyclopropanation of alpha-diazo ketones with gamma and delta double bonds. The ee values are significantly dependent on the solvent used; the best results are obtained using pentane." @default.
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- W2000925564 date "2001-09-18" @default.
- W2000925564 modified "2023-10-05" @default.
- W2000925564 title "High Enantiocontrol in the Intramolecular Cyclopropanation of Diazo Ketones Catalyzed by Dirhodium(II) Complexes with<i> Ortho-</i>Metalated Aryl Phosphine Ligands" @default.
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- W2000925564 doi "https://doi.org/10.1021/ol010170w" @default.
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