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- W2000928211 abstract "This paper reports work designed to establish the reliability of the gas chromatographic method for the determination of the mixed second virial coefficients B12 of mixtures of hydrocarbon vapours and permanent gases, and of activity coefficients γ∞1 at infinite dilution in hydrocarbon liquid mixtures. This work confirms for eight carrier gases that, except for CO and methane, the activity coefficients are independent of carrier gas employed to within about ±0.003 in log10γ. The values of B12, determined with three stationary phases, agree to within about ± 10 cm3 mole–1; in five cases comparison was possible with values of B12 obtained by independent experimental methods and agreement within the above limits was found." @default.
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- W2000928211 date "1968-01-01" @default.
- W2000928211 modified "2023-09-25" @default.
- W2000928211 title "Thermodynamics of mixtures from gas chromatography. The activity coefficients of hydrocarbon solutions and the second virial coefficients of hydrocarbon vapour and permanent gas mixtures" @default.
- W2000928211 doi "https://doi.org/10.1039/tf9686402667" @default.
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