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- W2000937372 abstract "From X-ray and neutron diffraction work with single crystals and powders we found two phase transitions at Tc1 = 260.5 ± 1 K and at Tc2 = 255 ± 1 K. The transition at Tc1 is characterised by the occurence of superstructure reflections breaking the f.c.c. translational symmetry, whereas the second one at Tc2 is indicated by a monoclinic lattice distortion without any further loss of translational symmetry. Both transitions can be explained by the softening of optical branches at the X- and the Γ-point of the Brillouin zone, corresponding to librations of the SnCl6-octahedra. Evidence for this low energy phonon branch is offered from the observation of diffuse streaks with X-rats and from their inelastic nature as revealed by the neutron triple axes technique." @default.
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- W2000937372 date "1976-12-01" @default.
- W2000937372 modified "2023-09-26" @default.
- W2000937372 title "X-ray and neutron investigations of the phase instabilities in K2SnCl6" @default.
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- W2000937372 doi "https://doi.org/10.1016/0038-1098(76)90496-8" @default.
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