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- W2000940669 abstract "Electronic structures of AMo5O8 (A=rare earth, alkaline earth) and the solid solution Sr1−xLaxMo5O8 (x=0–1) were examined using the extended Hückel tight binding method. AMo5O8 phases with divalent A cations (A=Sr, Ca, Eu) are normal semiconductors with small band gap. The Fermi surfaces of Sr1−xLaxMo5O8 (0.0<x≤1.0) and LnMo5O8 (Ln=trivalent rare earth) do not exhibit any nesting. In the electronic structures of LnMo5O8 (Ln=trivalent rare earth) phases, the Fermi level is dominated by the d-orbitals of the Mo(2) atoms of their Mo10 clusters. With decreasing x from 1.0 in Sr1−xLaxMo5O8, the dominance of the Mo(2) atoms at the Fermi level sharply diminishes. Based on this observation, we proposed a probable reason for the weakly semiconducting state above 180 K and the metallic state below 180 K in LnMo5O8 (Ln=trivalent rare earth)." @default.
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- W2000940669 date "1998-10-01" @default.
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- W2000940669 title "On the origin of the anomalous electrical resistivity of LnMo5O8 (Ln=TRIVALENT rare earth)" @default.
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