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- W2000942452 abstract "Abstract A new divergent synthesis of (+)- and (−)-ferruginine 4, via the optically active 8-benzyl-3-oxo-8-azabicyclo[3.2.1]octane-2-carboxylates 6 is described. The β-keto ester intermediates 6 were prepared by a novel PLE-catalyzed asymmetric dealkoxycarbonylation of the symmetric tropinone-type diesters 5. The key problem in the synthesis is controlling the regioselectivity of the reaction at the 2- and 4-positions in the tropane framework of the β-keto ester 6 for introduction of the acetyl group." @default.
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- W2000942452 date "2002-10-01" @default.
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- W2000942452 title "A new divergent synthesis of (+)- and (−)-ferruginine utilizing PLE-catalyzed asymmetric dealkoxycarbonylation" @default.
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