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- W2000949250 abstract "The in vivo hydrocarbon biosynthesis in the millipede Graphidostreptus tumuliporus was studied after the injection of 1- 14 C-acetate, 16- 14 C-, and 1- 14 C-palmitic acid. From all precursors used an active incorporation into the unsaturated hyrocarbons (alk-1-enes, alkadienes, and alkatrienes) was observed, whereas no radioactivity was incorporated into the saturated alkanes at all, in accordance with their supposed exogenous origin (food). From the distribution of the radiolabel over both the various hydrocarbon classes and the individual hydrocarbon components it was concluded that in this millipede hydrocarbons are synthesized from fatty acids (irrespective of their chain structure) by an elongation-decarboxylation mechanism in which an α-oxidation step is involved, whilst during the decarboxylation process a terminal double bond is introduced. Thus, saturated fatty acids give rise to alk-1-enes (as is evidenced by an overwhelming incorporation of palmitic acid into the alk-1-enes), monoenoic fatty acids to alkadienes, and dienoic fatty acids to alkatrienes. The proposed mechanism for hydrocarbon biosynthesis in G. tumuliporus has not yet been described in other organisms." @default.
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- W2000949250 date "1973-11-01" @default.
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- W2000949250 title "The biosynthesis of the hydrocarbons in males and females of the millipede Graphidostreptus tumuliporus" @default.
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- W2000949250 doi "https://doi.org/10.1016/0022-1910(73)90140-6" @default.
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