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• W2000950395 abstract "A model for a second harmonic generation (SHG) at the metal/electrolyte interface is proposed and treated by an electron density functional calculation. The dependence of the SHG signal on the electrode charge, σ, is studied for different values of system parameters which represent different aspects of metal—medium interaction. Characteristic differences between the SHG signal at a free metal surface and at the same metal in contact with an electrolyte are predicted in the range of negative charges and near the zero charge point. “Fundamental” trends in the signal changes upon ionic adsorption are established." @default.
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• W2000950395 date "1991-01-01" @default.
• W2000950395 modified "2023-10-18" @default.
• W2000950395 title "Theory of the Second Harmonic Generation at the Metal/Electrolyte Interface" @default.
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• W2000950395 doi "https://doi.org/10.1016/0013-4686(91)85053-a" @default.
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