Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000950824> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2000950824 endingPage "194" @default.
- W2000950824 startingPage "191" @default.
- W2000950824 abstract "Photoinduced electron transfer (charge separation (CS)) and back electron transfer (charge recombination (CR)) were investigated in the temperature range 7–320 K for the following acceptor-photosensitizer-donor hetero Langmuir-Blodgett film device: indium tin oxide/insulator layer (185 Å)/ two layers of steroidal tetracyano-p-quinodimethane (acceptor) (36 Å)/two layers of a Cu phthalocyanine derivative (photosensitizer (S)) (28 Å)/two layers of steroidal p-phenylenediamine (donor) (48 Å)/insulator layer (380 Å)/Al. The transient photocurrent in the CS process did not change very much in the temperature range observed. The apparent first-order rate constant kCR, obtained from the differential of the film voltage decay curve, decreased as CR proceeded. Arrhenius plots of kCR at various CR probabilities P indicated that both the thermal activation of reactant oscillators and the quantum-mechanical nuclear tunneling process existed, and that the former was predominant at high temperatures. The in-plane amorphous structures of monomolecular dye films can be considered to cause an activation energy distribution, which became wider as the temperature decreased, and also to cause a wide tunneling rate distribution. An irreversible decrement in the initial photovoltage occurred at 320 K, probably owing to glass transitions of the acceptor and insulator films. Similarities to electron transfer behaviors in natural photosynthetic reaction centers are also discussed." @default.
- W2000950824 created "2016-06-24" @default.
- W2000950824 creator A5023151460 @default.
- W2000950824 creator A5057550153 @default.
- W2000950824 date "1994-04-01" @default.
- W2000950824 modified "2023-09-23" @default.
- W2000950824 title "Photogenerated charge storage in hetero Langmuir-Blodgett films: Electron transfer mechanism" @default.
- W2000950824 cites W1971092996 @default.
- W2000950824 cites W1988394229 @default.
- W2000950824 cites W2004113895 @default.
- W2000950824 cites W2005515060 @default.
- W2000950824 cites W2016457555 @default.
- W2000950824 cites W2017214257 @default.
- W2000950824 cites W2024612532 @default.
- W2000950824 cites W2031083386 @default.
- W2000950824 cites W2047625091 @default.
- W2000950824 cites W2051523687 @default.
- W2000950824 cites W2078885959 @default.
- W2000950824 cites W2080876805 @default.
- W2000950824 cites W2095216354 @default.
- W2000950824 cites W2952585162 @default.
- W2000950824 doi "https://doi.org/10.1016/0040-6090(94)90528-2" @default.
- W2000950824 hasPublicationYear "1994" @default.
- W2000950824 type Work @default.
- W2000950824 sameAs 2000950824 @default.
- W2000950824 citedByCount "3" @default.
- W2000950824 crossrefType "journal-article" @default.
- W2000950824 hasAuthorship W2000950824A5023151460 @default.
- W2000950824 hasAuthorship W2000950824A5057550153 @default.
- W2000950824 hasConcept C113196181 @default.
- W2000950824 hasConcept C120398109 @default.
- W2000950824 hasConcept C121332964 @default.
- W2000950824 hasConcept C123669783 @default.
- W2000950824 hasConcept C147789679 @default.
- W2000950824 hasConcept C178790620 @default.
- W2000950824 hasConcept C180235531 @default.
- W2000950824 hasConcept C185592680 @default.
- W2000950824 hasConcept C192562407 @default.
- W2000950824 hasConcept C26873012 @default.
- W2000950824 hasConcept C2779892579 @default.
- W2000950824 hasConcept C2781018080 @default.
- W2000950824 hasConcept C2900893 @default.
- W2000950824 hasConcept C49040817 @default.
- W2000950824 hasConcept C55493867 @default.
- W2000950824 hasConcept C7070889 @default.
- W2000950824 hasConcept C75473681 @default.
- W2000950824 hasConcept C95121573 @default.
- W2000950824 hasConceptScore W2000950824C113196181 @default.
- W2000950824 hasConceptScore W2000950824C120398109 @default.
- W2000950824 hasConceptScore W2000950824C121332964 @default.
- W2000950824 hasConceptScore W2000950824C123669783 @default.
- W2000950824 hasConceptScore W2000950824C147789679 @default.
- W2000950824 hasConceptScore W2000950824C178790620 @default.
- W2000950824 hasConceptScore W2000950824C180235531 @default.
- W2000950824 hasConceptScore W2000950824C185592680 @default.
- W2000950824 hasConceptScore W2000950824C192562407 @default.
- W2000950824 hasConceptScore W2000950824C26873012 @default.
- W2000950824 hasConceptScore W2000950824C2779892579 @default.
- W2000950824 hasConceptScore W2000950824C2781018080 @default.
- W2000950824 hasConceptScore W2000950824C2900893 @default.
- W2000950824 hasConceptScore W2000950824C49040817 @default.
- W2000950824 hasConceptScore W2000950824C55493867 @default.
- W2000950824 hasConceptScore W2000950824C7070889 @default.
- W2000950824 hasConceptScore W2000950824C75473681 @default.
- W2000950824 hasConceptScore W2000950824C95121573 @default.
- W2000950824 hasIssue "1-2" @default.
- W2000950824 hasLocation W20009508241 @default.
- W2000950824 hasOpenAccess W2000950824 @default.
- W2000950824 hasPrimaryLocation W20009508241 @default.
- W2000950824 hasRelatedWork W1967318118 @default.
- W2000950824 hasRelatedWork W2031205912 @default.
- W2000950824 hasRelatedWork W2038760641 @default.
- W2000950824 hasRelatedWork W2042550551 @default.
- W2000950824 hasRelatedWork W2044604875 @default.
- W2000950824 hasRelatedWork W2118124394 @default.
- W2000950824 hasRelatedWork W2161660476 @default.
- W2000950824 hasRelatedWork W2485326446 @default.
- W2000950824 hasRelatedWork W4297518758 @default.
- W2000950824 hasRelatedWork W61630102 @default.
- W2000950824 hasVolume "242" @default.
- W2000950824 isParatext "false" @default.
- W2000950824 isRetracted "false" @default.
- W2000950824 magId "2000950824" @default.
- W2000950824 workType "article" @default.