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- W2000951025 abstract "This work seeks to characterize the influence of chloride on the surface-enhanced Raman scattering (SERS), optical absorption and fluorescence of methyl orange adsorbed on Ag colloids. The relation between SERS, absorption and fluorescence signals points out the importance of a first-layer effect to account for the changes in intensity and in the spectral profile observed when adding Cl−. A differing response of the Ag colloids to the excitation wavelength in presence or absence of Cl− indicates the influence of the halide on the morphology of the metal particles and subsequently the surface-coverage of adsorbate. The differences observed in the profiles of first-layer SERS spectra and the multilayer spectra may be attributed to a considerable contribution of the charge-transfer mechanism to the SERS effect, which is more efficient in the first-layer." @default.
- W2000951025 created "2016-06-24" @default.
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- W2000951025 date "2006-10-01" @default.
- W2000951025 modified "2023-10-16" @default.
- W2000951025 title "Influence of coverage and adsorption orientation in the spectroscopy of methyl orange on silver colloids: Cl− effect" @default.
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- W2000951025 doi "https://doi.org/10.1016/j.cplett.2006.08.054" @default.
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