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- W2000956089 abstract "The reactive uptake of ClONO2 on liquid sulfuric acid has been measured for size-selected, sub-micron aerosol in the composition range 36–54% H2SO4 by weight at ≈ 250 K. A comparison with results from studies employing bulk surfaces at similar temperatures and compositions shows no evidence for a dependence of the reaction probability, γ, on size. We use this observation to estimate an upper limit to the diffuso-reactive length of 26 nm for the ClONO2 + H2O reaction on 43 weight % aerosol at 248 K. But, the present values of γ are consistently lower than bulk values observed at lower temperatures and similar composition, suggesting that γ is temperature dependent." @default.
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- W2000956089 date "1998-09-01" @default.
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- W2000956089 title "The hydrolysis of ClONO<sub>2</sub>on sub-micron liquid sulfuric acid aerosol" @default.
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- W2000956089 doi "https://doi.org/10.1029/98gl02566" @default.
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