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- W2000960013 abstract "[Au(CH2)2PPH2]2, (1), reacts with neat CH2ClBr to give [Au(CH2)2PPH2]2(CH2Cl)Br, (2), and the X-ray structure of (2), shows a close contact between one Au centre and the Cl of the co-ordinated CH2Cl [2.895(16)Ă]; this interaction is consistent with the observed further oxidative addition of the CH2Cl to form the bridging methylene A-frame complex, and suggests that a carbene intermediate may be involved." @default.
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- W2000960013 date "1985-01-01" @default.
- W2000960013 modified "2023-10-11" @default.
- W2000960013 title "Characterization of the gold(II) dimer [Au(CH2)2PPh2]2(CH2Cl)Br: structural evidence suggesting the formation of a carbene intermediate preceeding A-frame (bridging methylene) formation" @default.
- W2000960013 doi "https://doi.org/10.1039/c39850001278" @default.
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