Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000960062> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2000960062 endingPage "9543" @default.
- W2000960062 startingPage "9535" @default.
- W2000960062 abstract "The structural isomers formed by the homogeneous rhodium-catalyzed isomerization of several vegetable oils have been elucidated. A detailed study of the isomerization of the model compound methyl linoleate has been performed to correlate the distribution of conjugated isomers, the reaction kinetics, and the mechanism of the reaction. It has been shown that [RhCl(C8H8)2]2 is a highly efficient and selective isomerization catalyst for the production of highly conjugated vegetable oils with a high conjugated linoleic acid (CLA) content, which is highly desirable in the food industry. The combined fraction of the two major CLA isomers [(9Z,11E)-CLA and (10E,12Z)-CLA] in the overall CLA mixture is in the range from 76.2% to 93.4%. The high efficiency and selectivity of this isomerization method along with the straightforward purification process render this approach highly promising for the preparation of conjugated oils and CLA. Proposed improvements in catalyst recovery and reusability will only make this method more appealing to the food, paint, coating, and polymer industries in the future. Keywords: Conjugated linoleic acid; conjugated vegetable oils; homogeneous rhodium-catalyzed isomerization; structural isomers" @default.
- W2000960062 created "2016-06-24" @default.
- W2000960062 creator A5032945914 @default.
- W2000960062 creator A5061187623 @default.
- W2000960062 creator A5069286886 @default.
- W2000960062 creator A5090195617 @default.
- W2000960062 date "2006-11-17" @default.
- W2000960062 modified "2023-09-24" @default.
- W2000960062 title "Elucidation of Structural Isomers from the Homogeneous Rhodium-Catalyzed Isomerization of Vegetable Oils" @default.
- W2000960062 cites W1972310886 @default.
- W2000960062 cites W1976650585 @default.
- W2000960062 cites W1994550004 @default.
- W2000960062 cites W1996896024 @default.
- W2000960062 cites W2004246929 @default.
- W2000960062 cites W2009496929 @default.
- W2000960062 cites W2015238811 @default.
- W2000960062 cites W2024827610 @default.
- W2000960062 cites W2030153690 @default.
- W2000960062 cites W2035224982 @default.
- W2000960062 cites W2071485149 @default.
- W2000960062 cites W2080988955 @default.
- W2000960062 cites W2088436316 @default.
- W2000960062 cites W2089418276 @default.
- W2000960062 cites W2315819250 @default.
- W2000960062 cites W2316427967 @default.
- W2000960062 cites W2328978728 @default.
- W2000960062 cites W4205445437 @default.
- W2000960062 cites W4233893028 @default.
- W2000960062 cites W4255285139 @default.
- W2000960062 doi "https://doi.org/10.1021/jf0612124" @default.
- W2000960062 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17147443" @default.
- W2000960062 hasPublicationYear "2006" @default.
- W2000960062 type Work @default.
- W2000960062 sameAs 2000960062 @default.
- W2000960062 citedByCount "43" @default.
- W2000960062 countsByYear W20009600622012 @default.
- W2000960062 countsByYear W20009600622013 @default.
- W2000960062 countsByYear W20009600622014 @default.
- W2000960062 countsByYear W20009600622015 @default.
- W2000960062 countsByYear W20009600622016 @default.
- W2000960062 countsByYear W20009600622017 @default.
- W2000960062 countsByYear W20009600622018 @default.
- W2000960062 countsByYear W20009600622020 @default.
- W2000960062 countsByYear W20009600622021 @default.
- W2000960062 countsByYear W20009600622023 @default.
- W2000960062 crossrefType "journal-article" @default.
- W2000960062 hasAuthorship W2000960062A5032945914 @default.
- W2000960062 hasAuthorship W2000960062A5061187623 @default.
- W2000960062 hasAuthorship W2000960062A5069286886 @default.
- W2000960062 hasAuthorship W2000960062A5090195617 @default.
- W2000960062 hasConcept C112613896 @default.
- W2000960062 hasConcept C126661725 @default.
- W2000960062 hasConcept C161790260 @default.
- W2000960062 hasConcept C178790620 @default.
- W2000960062 hasConcept C185592680 @default.
- W2000960062 hasConcept C202235601 @default.
- W2000960062 hasConcept C2779780233 @default.
- W2000960062 hasConcept C2780809830 @default.
- W2000960062 hasConcept C521398313 @default.
- W2000960062 hasConcept C521977710 @default.
- W2000960062 hasConcept C543025807 @default.
- W2000960062 hasConceptScore W2000960062C112613896 @default.
- W2000960062 hasConceptScore W2000960062C126661725 @default.
- W2000960062 hasConceptScore W2000960062C161790260 @default.
- W2000960062 hasConceptScore W2000960062C178790620 @default.
- W2000960062 hasConceptScore W2000960062C185592680 @default.
- W2000960062 hasConceptScore W2000960062C202235601 @default.
- W2000960062 hasConceptScore W2000960062C2779780233 @default.
- W2000960062 hasConceptScore W2000960062C2780809830 @default.
- W2000960062 hasConceptScore W2000960062C521398313 @default.
- W2000960062 hasConceptScore W2000960062C521977710 @default.
- W2000960062 hasConceptScore W2000960062C543025807 @default.
- W2000960062 hasIssue "25" @default.
- W2000960062 hasLocation W20009600621 @default.
- W2000960062 hasLocation W20009600622 @default.
- W2000960062 hasOpenAccess W2000960062 @default.
- W2000960062 hasPrimaryLocation W20009600621 @default.
- W2000960062 hasRelatedWork W1994856192 @default.
- W2000960062 hasRelatedWork W2015238811 @default.
- W2000960062 hasRelatedWork W2021926520 @default.
- W2000960062 hasRelatedWork W2039538828 @default.
- W2000960062 hasRelatedWork W2046186602 @default.
- W2000960062 hasRelatedWork W2058402996 @default.
- W2000960062 hasRelatedWork W2066997627 @default.
- W2000960062 hasRelatedWork W2944145603 @default.
- W2000960062 hasRelatedWork W2967989016 @default.
- W2000960062 hasRelatedWork W50502515 @default.
- W2000960062 hasVolume "54" @default.
- W2000960062 isParatext "false" @default.
- W2000960062 isRetracted "false" @default.
- W2000960062 magId "2000960062" @default.
- W2000960062 workType "article" @default.