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- W2000963208 abstract "Abstract The formation of the cyclic trisilyloxonium ion is observed by the 29 Si-NMR spectroscopy as a result of hydride transfer reaction between triethylsilane and Ph 3 C + B(C 6 F 5 ) 4 − in the presence of octamethyl-1,4-dioxatetrasilacyclohexane, 2 D 2 . This ion is transformed by the reaction with another 2 D 2 molecule into the cyclic trisilyloxonium ion at the polymer chain end. The mechanism of polymerisation of 2 D 2 is discussed in relation with the mechanism of polymerisation of cyclic siloxanes." @default.
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- W2000963208 date "2003-11-01" @default.
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- W2000963208 title "Tertiary trisilyloxonium ion in cationic ring-opening polymerisation of a model cyclic siloxane, octamethyl-1,4-dioxatetrasilacyclohexane" @default.
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- W2000963208 doi "https://doi.org/10.1016/s0022-328x(03)00452-2" @default.
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