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- W2000966257 abstract "The ligands [Ph 2 P(O)NP(E)Ph 2 ] − (E=S I; E=Se II) can readily be complexed to a range of palladium(II) starting materials affording new six-membered Pd–O–P–N–P–E palladacycles. Hence ligand substitution reaction of the chloride complexes [PdCl 2 (bipy)] (bipy=2,2′-bipyridine), [{Pd( μ -Cl)(L–L)} 2 ] (HL–L=C 9 H 13 N or C 12 H 13 N), [{Pd( μ -Cl)Cl(PMe 2 Ph)} 2 ] or [PdCl 2 (PR 3 ) 2 ] [PR 3 =PPh 3 ; 2PR 3 =Ph 2 PCH 2 CH 2 PPh 2 or cis -Ph 2 PCH=CHPPh 2 ] with either I (or II) in thf or CH 3 OH gave [Pd{Ph 2 P(O)NP(E)Ph 2 - O,E }(bipy)]PF 6 , [Pd{Ph 2 P(O)NP(E)Ph 2 - O , E }(L–L)], [Pd{Ph 2 P(O)NP(E)Ph 2 - O , E }Cl(PMe 2 Ph)] or [Pd{Ph 2 P(O)NP(E)Ph 2 - O , E } (PR 3 ) 2 ]PF 6 in good yields. All compounds described have been characterised by a combination of multinuclear NMR [31 P{1 H} and 1 H] and IR spectroscopy and microanalysis. The molecular structures of five complexes containing the selenium ligand II have been determined by single-crystal X-ray crystallography. Three different ring conformations were observed, a pseudo-butterfly, hinge and in the case of all three PR 3 complexes, pseudo-boat conformations. Within the Pd–O–P–N–P–Se rings there is evidence for π -electron delocalisation." @default.
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- W2000966257 date "1998-11-01" @default.
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- W2000966257 title "Synthesis and conformational studies of palladium(II) complexes containing [Ph2P(O)NP(E)Ph2]− (E=S or Se)" @default.
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- W2000966257 doi "https://doi.org/10.1016/s0277-5387(98)00253-8" @default.
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