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- W2000966464 abstract "The Raman spectra of selenium oxide difluoride, dichloride, dibromide, chloride fluoride and bromide chloride have been measured in solid and liquid phases and in solution in acetonitrile (MeCN). In all cases, as the state of molecular aggregation increases, the SeO stretching frequency falls, indicating the formation of oxygen bridges. Vibrational assignments are given for selenium oxide dibromide, bromide chloride and chloride fluoride and force constants have been calculated for all of the selenium oxide halides. The degree of formation of selenium oxide fluoride from selenium oxide dichloride and difluoride is shown to be less than that of selenium oxide bromide chloride from the dibromide and dichloride and this attributed to the importance of the back bonding mechanism in SeF bonds, which favours increased SeF bond strength when the second halogen is fluorine instead of chlorine, a mechanism which is not as significant for SECl and SeBr bonds." @default.
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- W2000966464 date "1982-01-01" @default.
- W2000966464 modified "2023-10-03" @default.
- W2000966464 title "Raman spectra of seleninyl halides" @default.
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- W2000966464 doi "https://doi.org/10.1016/0584-8539(82)80148-7" @default.
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