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- W2000966643 abstract "A novel polyurethane iniferter, synthesized from equal moles of toluene diisocyanate and 1,1,2,2-tetraphenyl-1,2-ethanediol, was used to polymerize acrylonitrile to assess whether it proceeded via a “living” radical polymerization mechanism. From the kinetic results, the rate of polymerization could be expressed as Rpα[BPT]0.96[AN]1.64. The increase of number-average molecular weight with increase of both conversion and polymerization time, the bimodal molecular weight distribution in gel permeation chromatography and the increase of molecular weight in the post-polymerization of polyacrylonitrile confirm that the present tetraphenylethane-based polyurethane iniferter follows a “living” radical polymerization mechanism. © 1996 John Wiley & Sons, Inc." @default.
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- W2000966643 date "1996-07-15" @default.
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- W2000966643 title "Tetraphenylethane iniferters. II. Toluene diisocyanate-based polyurethane iniferter for “living” radical polymerization of acrylonitrile" @default.
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- W2000966643 doi "https://doi.org/10.1002/(sici)1099-0518(19960715)34:9<1723::aid-pola9>3.0.co;2-s" @default.
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