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- W2000970227 abstract "Homocuprates R2CuMgX and heterocuprates [RCuBr]MgX can be reacted easily with 1-alkynylphosphines R′-C≡C-P(C6H5)2 (R′ = H or CH3), leading exclusively to vinylic phosphines RR′CCHP(C6H5)2 after protonation, in almost quantitative yields. The additions proved to be stereospecific, only cis-additions were observed as was shown by 1H-NMR and GLC." @default.
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- W2000970227 date "2010-09-02" @default.
- W2000970227 modified "2023-10-09" @default.
- W2000970227 title "Stereospecific addition of organocopper(I) reagents to 1-alkynylphosphines. A new example of α-hetero-substituted vinylcopper(I) compounds" @default.
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- W2000970227 doi "https://doi.org/10.1002/recl.19760950504" @default.
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