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- W2000973824 abstract "Two methods of linking racemic 2,3-dideoxypent-2-enopyranos-4-ulose to suitably protected monosaccharide derivatives have been evaluated. The resulting diastereoisomeric mixtures containing d-glucose, d-galactose, and l-rhamnose derivatives in the “aglycon” part were fractionated, and configurations were assigned to ten disaccharide precursors. Disaccharides containing non-reducing 2,3-dideoxy-α-d- and -α-l-pent-2-enopyranose residues and their saturated analogues have been obtained by lithium aluminum hydride reduction of selected pentosylulose-mono-saccharides. Inversion of configuration at the allylic position (C-4) in some unsaturated disaccharides is also described." @default.
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- W2000973824 date "1980-01-01" @default.
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- W2000973824 title "Synthesis of some disaccharides containing pent-2-enopyranose residues" @default.
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- W2000973824 doi "https://doi.org/10.1016/s0008-6215(00)85314-8" @default.
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