FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000975727> ?p ?o ?g. }

• W2000975727 endingPage "2431" @default.
• W2000975727 startingPage "2431" @default.
• W2000975727 abstract "Two novel phenyl esters and partial phenyl esters of (dicloromethylene)bisphosphonic acid were synthesised. Three new layered Cd complexes of (dichloromethylene)bisphosphonic acidP,P-diphenyl, monophenyl and monoethyl esters were prepared. The complexes, [Cd3{(Cl2CP2O6Ph)2(H3COH)(H2O)5}(H2O)2]n (7), [{Cd(Cl2CP2O6Ph2)(H2O)3}(H2O)]n (8) and [{Cd1.5(Cl2CP2O6Et)(H2O)2}(C3H6O)0.5(H2O)4.5]n (9), were characterized by single crystal X-ray diffraction, IR spectroscopy, solid-state 31P- and 113Cd-CP/MAS NMR and elemental analysis. Also their thermal behaviour was investigated. Compound 7 consists of 1D chains with four independent octahedral Cd atoms joined by two L1 ligands, L1 = (Cl2CP2O6Ph)3−. The chains are connected into layers by phosphonate O atoms, and the adjacent layers are held together by face-to-face π–π stacking interactions. Compound 8 shows a new type of layered structure for metal bisphosphonates, where the L2 ligand, L2 = (Cl2CP2O6Ph2)2−, coordinates tridentately to three Cd2+ ions. Each CdO6 octahedron is connected to three CPO3 tetrahedra and each tetrahedron to three octahedra leading to a 2-D framework consisting of 12-membered cyclic cores. The layers are held together by edge-to-face CH/π interactions. In compound 9, the asymmetric unit contains two independent Cd2+ cations connected by L3 ligands, L3 = (Cl2CP2O6Et)3– and aqua ligands, to form a Cd–bisphosphonate layer. The layers are further interconnected into a 3-D supramolecular network by extensive hydrogen bonds." @default.
• W2000975727 created "2016-06-24" @default.
• W2000975727 creator A5022117953 @default.
• W2000975727 creator A5023656414 @default.
• W2000975727 creator A5060640651 @default.
• W2000975727 creator A5088272654 @default.
• W2000975727 creator A5089321496 @default.
• W2000975727 date "2009-01-01" @default.
• W2000975727 modified "2023-10-10" @default.
• W2000975727 title "Synthesis of phenyl substituted bisphosphonates and crystal structures and characterization of Cd complexes of (dichloromethylene)bisphosphonic acid phenyl and alkyl ester derivatives" @default.
• W2000975727 cites W1897499866 @default.
• W2000975727 cites W1963573116 @default.
• W2000975727 cites W1973092087 @default.
• W2000975727 cites W1982621298 @default.
• W2000975727 cites W1984131196 @default.
• W2000975727 cites W1990052278 @default.
• W2000975727 cites W1990986101 @default.
• W2000975727 cites W1992248286 @default.
• W2000975727 cites W1996021090 @default.
• W2000975727 cites W2000616607 @default.
• W2000975727 cites W2006950202 @default.
• W2000975727 cites W2010333642 @default.
• W2000975727 cites W2021563247 @default.
• W2000975727 cites W2029073410 @default.
• W2000975727 cites W2029239108 @default.
• W2000975727 cites W2030841140 @default.
• W2000975727 cites W2030937771 @default.
• W2000975727 cites W2031110465 @default.
• W2000975727 cites W2052845406 @default.
• W2000975727 cites W2060346406 @default.
• W2000975727 cites W2062552574 @default.
• W2000975727 cites W2065253200 @default.
• W2000975727 cites W2070298707 @default.
• W2000975727 cites W2075391102 @default.
• W2000975727 cites W2084827579 @default.
• W2000975727 cites W2085294032 @default.
• W2000975727 cites W2086247331 @default.
• W2000975727 cites W2090863562 @default.
• W2000975727 cites W2118781224 @default.
• W2000975727 cites W2125236428 @default.
• W2000975727 cites W2128087289 @default.
• W2000975727 cites W2131350133 @default.
• W2000975727 cites W2163048481 @default.
• W2000975727 cites W2167459367 @default.
• W2000975727 cites W2227375087 @default.
• W2000975727 cites W2335127589 @default.
• W2000975727 cites W290930486 @default.
• W2000975727 cites W2949121998 @default.
• W2000975727 cites W2949435162 @default.
• W2000975727 cites W2950482480 @default.
• W2000975727 cites W4235961421 @default.
• W2000975727 cites W4236023404 @default.
• W2000975727 doi "https://doi.org/10.1039/b907874f" @default.
• W2000975727 hasPublicationYear "2009" @default.
• W2000975727 type Work @default.
• W2000975727 sameAs 2000975727 @default.
• W2000975727 citedByCount "13" @default.
• W2000975727 countsByYear W20009757272012 @default.
• W2000975727 countsByYear W20009757272013 @default.
• W2000975727 countsByYear W20009757272014 @default.
• W2000975727 countsByYear W20009757272015 @default.
• W2000975727 countsByYear W20009757272016 @default.
• W2000975727 countsByYear W20009757272022 @default.
• W2000975727 countsByYear W20009757272023 @default.
• W2000975727 crossrefType "journal-article" @default.
• W2000975727 hasAuthorship W2000975727A5022117953 @default.
• W2000975727 hasAuthorship W2000975727A5023656414 @default.
• W2000975727 hasAuthorship W2000975727A5060640651 @default.
• W2000975727 hasAuthorship W2000975727A5088272654 @default.
• W2000975727 hasAuthorship W2000975727A5089321496 @default.
• W2000975727 hasConcept C112887158 @default.
• W2000975727 hasConcept C115624301 @default.
• W2000975727 hasConcept C116569031 @default.
• W2000975727 hasConcept C170493617 @default.
• W2000975727 hasConcept C178790620 @default.
• W2000975727 hasConcept C185592680 @default.
• W2000975727 hasConcept C198819137 @default.
• W2000975727 hasConcept C2777626080 @default.
• W2000975727 hasConcept C2780263894 @default.
• W2000975727 hasConcept C32909587 @default.
• W2000975727 hasConcept C33347731 @default.
• W2000975727 hasConcept C55493867 @default.
• W2000975727 hasConcept C71240020 @default.
• W2000975727 hasConcept C73922627 @default.
• W2000975727 hasConcept C8010536 @default.
• W2000975727 hasConcept C93275456 @default.
• W2000975727 hasConceptScore W2000975727C112887158 @default.
• W2000975727 hasConceptScore W2000975727C115624301 @default.
• W2000975727 hasConceptScore W2000975727C116569031 @default.
• W2000975727 hasConceptScore W2000975727C170493617 @default.
• W2000975727 hasConceptScore W2000975727C178790620 @default.
• W2000975727 hasConceptScore W2000975727C185592680 @default.
• W2000975727 hasConceptScore W2000975727C198819137 @default.
• W2000975727 hasConceptScore W2000975727C2777626080 @default.
• W2000975727 hasConceptScore W2000975727C2780263894 @default.
• W2000975727 hasConceptScore W2000975727C32909587 @default.
• W2000975727 hasConceptScore W2000975727C33347731 @default.
• W2000975727 hasConceptScore W2000975727C55493867 @default.

• next