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• W2000977887 abstract "Low-energy (5–80 eV) electron-stimulated desorption of H+ (D+), OH+ (OD+), O+, and NO+ from solution-grown NaNO3 crystals is studied by quadrupole and time-of-flight mass spectrometry. Desorption yields and thresholds are reported as a function of incident electron energy and flux. The O+ and NO+ are degradation products of the NaNO3 substrate, whereas the H+ (D+) and OH+ (OD+) ions arise primarily from -H(D) and/or -OH(OD) termination sites. The threshold energies indicate that degradation involves Auger-stimulated dissociation of the nitrate group. We associate the ∼24 eV threshold for H+ (D+) desorption with intramolecular decay of a single hole in the O(2s) level of either NaOH(OD), or possibly HNO3, terminal groups and the yield increase at ∼33 eV with intermolecular decay of the Na (2p→3s) exciton. We correlate the OH+(OD+), O+ and NO+ desorption thresholds at ∼33 eV primarily with excitation of the Na (2p→3s) exciton. Desorption of NO+ and O+ may also involve intramolecular Auger decay of holes in the 2e′ and/or 3a1′ nitrate valence bands. The H+ translational energy distributions peak at ∼5–7.5 eV, and H+ dominates the cation desorption yields from solution grown NaNO3 crystals by a factor of ∼100." @default.
• W2000977887 created "2016-06-24" @default.
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• W2000977887 date "1996-03-01" @default.
• W2000977887 modified "2023-10-14" @default.
• W2000977887 title "Low-energy (5–80 eV) electron-stimulated desorption of H+ (D+), OH+ (OD+), O+, and NO+ from solution-grown NaNO3 crystals" @default.
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• W2000977887 doi "https://doi.org/10.1016/0039-6028(95)00980-9" @default.
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