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- W2000980771 abstract "Photodegradation processes of carbocyanine dyes spin-coated on a polycarbonate plate were studied by steady-state photolysis and near-IR emission spectroscopy. The efficiency of the whole photodegradation caused by molecular oxygen directly and/or indirectly was found to strongly depend on both substituents on the 1 and 1‘ positions and the counterion. Singlet molecular oxygen (1Δg) produced at the interface between the dye thin film and a polycarbonate plate was detected by near-IR emission spectroscopy. Its yield did not depend on substituents on the 1 and 1‘ positions but on the counterion. The relative reactivity of carbocyanine dyes in the film state with the singlet molecular oxygen was estimated by exploiting a perinaphthenone thin film as a singlet molecular oxygen generator. The reactivity strongly depended on both substituents on the 1 and 1‘ positions and the counterion." @default.
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- W2000980771 date "2003-07-12" @default.
- W2000980771 modified "2023-09-27" @default.
- W2000980771 title "Photodegradation Processes of Cyanine Dyes in the Film State Induced by Singlet Molecular Oxygen" @default.
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- W2000980771 doi "https://doi.org/10.1021/jp027299n" @default.
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