FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000983552> ?p ?o ?g. }

• W2000983552 endingPage "338" @default.
• W2000983552 startingPage "325" @default.
• W2000983552 abstract "The hydrodenitrogenation of o-propylaniline on MoS2/γ-Al2O3 and NiMoS/γ-Al2O3 catalysts proceeds via two parallel routes, i.e., direct denitrogenation (DDN) by C(sp2)–N bond cleavage to form propylbenzene and hydrogenation (HYD) of the phenyl ring to form propylcyclohexylamine, followed by C(sp3)–N bond cleavage. Coordinatively unsaturated sites (CUS) at the edges of the sulfide slabs are catalytically active for the DDN. Dibenzothiophene (DBT) decreases the DDN rate, while it is mainly converted via direct desulfurization. Adding Ni to MoS2 increases the CUS concentration and promotes the HYD but inhibits the DDN, suggesting that Ni cations are not involved in the active sites for DDN route. Catalytically active sites for the HYD route are the sites at the basal plane near the edges of the sulfide slabs (brim sites). The presence of DBT strongly increases the HYD rate on NiMoS/γ-Al2O3, increasing the electron density at the brim sites due the electron pair donor properties of DBT and biphenyl." @default.
• W2000983552 created "2016-06-24" @default.
• W2000983552 creator A5039369575 @default.
• W2000983552 creator A5051053074 @default.
• W2000983552 creator A5057378771 @default.
• W2000983552 creator A5072595298 @default.
• W2000983552 date "2011-07-01" @default.
• W2000983552 modified "2023-09-23" @default.
• W2000983552 title "Selective poisoning of the direct denitrogenation route in o-propylaniline HDN by DBT on Mo and NiMo/γ-Al2O3 sulfide catalysts" @default.
• W2000983552 cites W138349728 @default.
• W2000983552 cites W1617176770 @default.
• W2000983552 cites W1963586498 @default.
• W2000983552 cites W1965531678 @default.
• W2000983552 cites W1969544215 @default.
• W2000983552 cites W1970669296 @default.
• W2000983552 cites W1974896731 @default.
• W2000983552 cites W1977760424 @default.
• W2000983552 cites W1979237384 @default.
• W2000983552 cites W1979957804 @default.
• W2000983552 cites W1983816476 @default.
• W2000983552 cites W1985695393 @default.
• W2000983552 cites W1986523195 @default.
• W2000983552 cites W1987817152 @default.
• W2000983552 cites W1994430879 @default.
• W2000983552 cites W1996857418 @default.
• W2000983552 cites W1997523739 @default.
• W2000983552 cites W1998241890 @default.
• W2000983552 cites W1998781321 @default.
• W2000983552 cites W2002452182 @default.
• W2000983552 cites W2009266937 @default.
• W2000983552 cites W2009834142 @default.
• W2000983552 cites W2013095940 @default.
• W2000983552 cites W2014394100 @default.
• W2000983552 cites W2014924331 @default.
• W2000983552 cites W2015334923 @default.
• W2000983552 cites W2018551209 @default.
• W2000983552 cites W2021011475 @default.
• W2000983552 cites W2024457262 @default.
• W2000983552 cites W2027188823 @default.
• W2000983552 cites W2030417277 @default.
• W2000983552 cites W2032341433 @default.
• W2000983552 cites W2033375108 @default.
• W2000983552 cites W2033887486 @default.
• W2000983552 cites W2038489341 @default.
• W2000983552 cites W2046552220 @default.
• W2000983552 cites W2047199097 @default.
• W2000983552 cites W2049421930 @default.
• W2000983552 cites W2054545055 @default.
• W2000983552 cites W2056746047 @default.
• W2000983552 cites W2057768609 @default.
• W2000983552 cites W2058629812 @default.
• W2000983552 cites W2059336871 @default.
• W2000983552 cites W2067464273 @default.
• W2000983552 cites W2068043331 @default.
• W2000983552 cites W2071977224 @default.
• W2000983552 cites W2075234573 @default.
• W2000983552 cites W2075357804 @default.
• W2000983552 cites W2078729482 @default.
• W2000983552 cites W2079093447 @default.
• W2000983552 cites W2079327015 @default.
• W2000983552 cites W2083619624 @default.
• W2000983552 cites W2085895639 @default.
• W2000983552 cites W2088591799 @default.
• W2000983552 cites W2089851961 @default.
• W2000983552 cites W2091159529 @default.
• W2000983552 cites W2111509237 @default.
• W2000983552 cites W2120497186 @default.
• W2000983552 cites W2130033504 @default.
• W2000983552 cites W2133795748 @default.
• W2000983552 cites W2135175049 @default.
• W2000983552 cites W2135779548 @default.
• W2000983552 cites W2149386806 @default.
• W2000983552 cites W2257411431 @default.
• W2000983552 cites W294900698 @default.
• W2000983552 cites W2949801026 @default.
• W2000983552 cites W2951458837 @default.
• W2000983552 cites W34986755 @default.
• W2000983552 cites W4211000185 @default.
• W2000983552 cites W4245893434 @default.
• W2000983552 cites W4252215861 @default.
• W2000983552 doi "https://doi.org/10.1016/j.jcat.2011.05.017" @default.
• W2000983552 hasPublicationYear "2011" @default.
• W2000983552 type Work @default.
• W2000983552 sameAs 2000983552 @default.
• W2000983552 citedByCount "50" @default.
• W2000983552 countsByYear W20009835522012 @default.
• W2000983552 countsByYear W20009835522013 @default.
• W2000983552 countsByYear W20009835522014 @default.
• W2000983552 countsByYear W20009835522015 @default.
• W2000983552 countsByYear W20009835522016 @default.
• W2000983552 countsByYear W20009835522017 @default.
• W2000983552 countsByYear W20009835522018 @default.
• W2000983552 countsByYear W20009835522019 @default.
• W2000983552 countsByYear W20009835522020 @default.
• W2000983552 countsByYear W20009835522021 @default.
• W2000983552 countsByYear W20009835522022 @default.
• W2000983552 countsByYear W20009835522023 @default.
• W2000983552 crossrefType "journal-article" @default.

• next