Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000986001> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2000986001 endingPage "99" @default.
- W2000986001 startingPage "91" @default.
- W2000986001 abstract "The Diels-Alder product from the reaction of methyl 2,3,6-trideoxy-α-d-glycero-hex-2-enopyranosid-4-ulose (1b) with trans-1-methoxy-3-tert-butyl-dimethylsilyloxy-1,3-butadiene is 3b (93%). Reaction of 3b with sodium borohydride causes reduction of the C-4 carbonyl group only, but, with lithium aluminum hydride, further reactions occur which can be rationalized by fragmentation brought about by hydride cleavage on the silicon-oxygen bond, with simultaneous ejection of the β-methoxyl group complexed to a trivalent aluminum species. The enone resulting from this fragmentation also reacts further with lithium aluminum hydride, and several products result. The behavior of postulated intermediates, which have been prepared separately and subjected to the reaction conditions, supports the proposed reaction mechanisms. The “second generation” enone (methyl 2,3,6-trideoxy-α-d-talopyranosido)-[3,2-d]-2-cyclohexenone (10a), arising from the first generation precursor 1b, has been prepared by two routes." @default.
- W2000986001 created "2016-06-24" @default.
- W2000986001 creator A5033559851 @default.
- W2000986001 creator A5040856142 @default.
- W2000986001 creator A5060905709 @default.
- W2000986001 creator A5067965356 @default.
- W2000986001 date "1985-02-01" @default.
- W2000986001 modified "2023-10-12" @default.
- W2000986001 title "Second generation α-enones from a pyranosidic α-enone" @default.
- W2000986001 cites W1979513828 @default.
- W2000986001 cites W1985213826 @default.
- W2000986001 cites W2013650360 @default.
- W2000986001 cites W2062727671 @default.
- W2000986001 cites W2070313090 @default.
- W2000986001 cites W2104596246 @default.
- W2000986001 cites W2318868082 @default.
- W2000986001 cites W2949088807 @default.
- W2000986001 cites W2950104407 @default.
- W2000986001 cites W3004417479 @default.
- W2000986001 cites W3004776919 @default.
- W2000986001 cites W3004940916 @default.
- W2000986001 cites W3004949021 @default.
- W2000986001 cites W3005115976 @default.
- W2000986001 cites W3005267481 @default.
- W2000986001 cites W4233271703 @default.
- W2000986001 doi "https://doi.org/10.1016/0008-6215(85)85188-0" @default.
- W2000986001 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/4005893" @default.
- W2000986001 hasPublicationYear "1985" @default.
- W2000986001 type Work @default.
- W2000986001 sameAs 2000986001 @default.
- W2000986001 citedByCount "6" @default.
- W2000986001 crossrefType "journal-article" @default.
- W2000986001 hasAuthorship W2000986001A5033559851 @default.
- W2000986001 hasAuthorship W2000986001A5040856142 @default.
- W2000986001 hasAuthorship W2000986001A5060905709 @default.
- W2000986001 hasAuthorship W2000986001A5067965356 @default.
- W2000986001 hasConcept C111919701 @default.
- W2000986001 hasConcept C134018914 @default.
- W2000986001 hasConcept C145148216 @default.
- W2000986001 hasConcept C155647269 @default.
- W2000986001 hasConcept C161790260 @default.
- W2000986001 hasConcept C178790620 @default.
- W2000986001 hasConcept C185592680 @default.
- W2000986001 hasConcept C191015642 @default.
- W2000986001 hasConcept C2777706827 @default.
- W2000986001 hasConcept C2777961443 @default.
- W2000986001 hasConcept C2778541603 @default.
- W2000986001 hasConcept C2779746879 @default.
- W2000986001 hasConcept C2780048404 @default.
- W2000986001 hasConcept C2908569058 @default.
- W2000986001 hasConcept C3044715 @default.
- W2000986001 hasConcept C41008148 @default.
- W2000986001 hasConcept C512968161 @default.
- W2000986001 hasConcept C71240020 @default.
- W2000986001 hasConcept C71924100 @default.
- W2000986001 hasConcept C75473681 @default.
- W2000986001 hasConceptScore W2000986001C111919701 @default.
- W2000986001 hasConceptScore W2000986001C134018914 @default.
- W2000986001 hasConceptScore W2000986001C145148216 @default.
- W2000986001 hasConceptScore W2000986001C155647269 @default.
- W2000986001 hasConceptScore W2000986001C161790260 @default.
- W2000986001 hasConceptScore W2000986001C178790620 @default.
- W2000986001 hasConceptScore W2000986001C185592680 @default.
- W2000986001 hasConceptScore W2000986001C191015642 @default.
- W2000986001 hasConceptScore W2000986001C2777706827 @default.
- W2000986001 hasConceptScore W2000986001C2777961443 @default.
- W2000986001 hasConceptScore W2000986001C2778541603 @default.
- W2000986001 hasConceptScore W2000986001C2779746879 @default.
- W2000986001 hasConceptScore W2000986001C2780048404 @default.
- W2000986001 hasConceptScore W2000986001C2908569058 @default.
- W2000986001 hasConceptScore W2000986001C3044715 @default.
- W2000986001 hasConceptScore W2000986001C41008148 @default.
- W2000986001 hasConceptScore W2000986001C512968161 @default.
- W2000986001 hasConceptScore W2000986001C71240020 @default.
- W2000986001 hasConceptScore W2000986001C71924100 @default.
- W2000986001 hasConceptScore W2000986001C75473681 @default.
- W2000986001 hasLocation W20009860011 @default.
- W2000986001 hasLocation W20009860012 @default.
- W2000986001 hasOpenAccess W2000986001 @default.
- W2000986001 hasPrimaryLocation W20009860011 @default.
- W2000986001 hasRelatedWork W1965117275 @default.
- W2000986001 hasRelatedWork W2000986001 @default.
- W2000986001 hasRelatedWork W2101573594 @default.
- W2000986001 hasRelatedWork W2148665700 @default.
- W2000986001 hasRelatedWork W2321351819 @default.
- W2000986001 hasRelatedWork W2335458542 @default.
- W2000986001 hasRelatedWork W2396729597 @default.
- W2000986001 hasRelatedWork W2408161143 @default.
- W2000986001 hasRelatedWork W2952879190 @default.
- W2000986001 hasRelatedWork W2346750330 @default.
- W2000986001 hasVolume "136" @default.
- W2000986001 isParatext "false" @default.
- W2000986001 isRetracted "false" @default.
- W2000986001 magId "2000986001" @default.
- W2000986001 workType "article" @default.