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- W2000988093 abstract "Thermal demercuration reactions of organomercurials (RHgX) alone or with mercuric salts (HgY2) were performed (where R=n-butyl, s-butyl, cyclohexyl, benzyl, phenyl, and p-tolyl; X,Y=Cl, Br, CN, SCN, and OAc). Alkyl chlorides were obtained in good yields in the cases of alkylmercuric chlorides. The results in the reactions of cyclohexylmercuric halides with mercuric salts suggested the exchange reaction between them. Thermal demercuration reactions of aryl-mercurials gave the corresponding aromatic hydrocarbons as main product, and their mechanisms which involve generation of aryl radicals were discussed. General mechanisms of demercuration reaction of organomercurials alone were also discussed, and the importance of intermolecular interaction between organic group and chlorine was suggested in the cases of aliphatic organo-mercuric chlorides." @default.
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- W2000988093 title "Thermal Demercuration Reactions of Organomercurials" @default.
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- W2000988093 doi "https://doi.org/10.1246/bcsj.43.2574" @default.
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