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- W2000989065 abstract "The reaction of hydrogen with carbon monoxide over Rh/Al/sub 2/O/sub 3/ and Rh/TiO/sub 2/ catalytic films, some of which contained potassium as an additive, has been investigated. The presence of potassium caused the usual gem dicarbonyl and linear CO species on supported rhodium to disappear at lower temperature than for catalysts containing no potassium. On the other hand, the bridged carbonyl species seemed to be significantly enhanced by the presence of potassium. the Rh/TiO/sub 2/ films to which potassium was added catalyzed the production of significant amounts of acetone and acetaldehyde as oxygenated products. It is likely that the bridged carbonyl species is the precursor to oxygenated products." @default.
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- W2000989065 date "1986-08-01" @default.
- W2000989065 modified "2023-09-26" @default.
- W2000989065 title "Effects of potassium on carbon monoxide methanation over supported rhodium films" @default.
- W2000989065 doi "https://doi.org/10.1021/j100409a001" @default.
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