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- W2000989268 abstract "Reaction of copper(I) chloride with thiophene-2-carbaldehyde thiosemicarbazone (Httsc) in acetonitrile in the presence of Ph3P yielded a sulfur-bridged dimer [Cu2Cl2(μ2-S-Httsc)2(PPh3)2] · 2CH3CN (1), while a similar reaction with isatin-3-thiosemicarbazone (H2itsc) formed a monomer, [CuCl(H2itsc)(Ph3P)2] · 2CH3CN (3). Furan-2-carbaldehyde thiosemicarbazone (Hftsc) also formed a compound of the composition [Cu2Cl2(Hftsc)2(PPh3)2] · 2H2O (2). Complexes 1–3 have been characterized using elemental analysis, IR, 1H and 31P NMR spectroscopy and single crystal X-ray crystallography (1 and 3). Acetonitrile is engaged in hydrogen bonding with the chlorine atom {NCCH2–H⋯Cl)}, which is necessary for the stabilization of the bridging sulfur in 1. In compound 3, however, acetonitrile is strongly hydrogen bonded to the NH hydrogen of the isatin ring {CH3CN⋯NH(isatin)} and not to the chlorine atom. The Cu⋯Cu contact of 2.7719(5) Å in dimer 1 is close to twice the van der Waals radius of the Cu atom (2.80 Å)." @default.
- W2000989268 created "2016-06-24" @default.
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- W2000989268 date "2007-07-01" @default.
- W2000989268 modified "2023-10-02" @default.
- W2000989268 title "Synthesis and structures of monomeric [chloro(isatin-3-thiosemicarbazone)bis(triphenylphosphine)]copper(I) and dimeric [dichlorobis(thiophene-2-carbaldehyde thiosemicarbazone)bis(triphenylphosphine)]dicopper(I)] complexes" @default.
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- W2000989268 doi "https://doi.org/10.1016/j.poly.2006.12.044" @default.
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