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- W2000990370 abstract "Abstract BaTiAl6O12 crystallizes in the orthorhombic system with unit-cell dimensions a = 4.862(1), b = 7.136(2), c = 13.598(3) A and space group Pnnm with z = 2. The structure was solved by Patterson and Fourier methods. Of the 714 unique reflections measured by counter techniques, 253 with I > 3σ(I) were used in the least-squares refinement of the model to a conventional R of 0.042 (Rw = 0.037). The structure of BaTiAl6O12 consists of octahedra (mixed Ti and Al occupancy) and tetrahedra (all Al) in a three-dimensional array forming tunnels in which barium ions are located. The octahedra form ribbons or strings by edge-sharing to one another, and are corner-shared to tetrahedra. The corner-shared array of tetrahedra links the ribbons of octahedra. Ba3TiAl10O20 crystallizes in the monoclinic system with unit-cell dimensions a = 15.631(4), b = 11.373(2), and c = 4.981(1) A, β = 107.77(2)°, and space group C2 m with z = 2. The structure was solved by Patterson and Fourier methods and of the 2909 unique reflections measured by counter techniques, 1561 with I > 3σ(I) were used in the least-squares refinement of the model to a conventional R of 0.046 (Rw = 0.042). The structure consists of sheets of corner-shared tetrahedra linked by parallel ribbons of edge-shared octahedra. (The octahedra are of mixed Ti and Al occupancy.) The barium ions are located in tunnels of two different types." @default.
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- W2000990370 date "1985-11-01" @default.
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- W2000990370 title "Single crystal structure determinations of BaTiAl6O12 and Ba3TiAl10O20" @default.
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- W2000990370 doi "https://doi.org/10.1016/0022-4596(85)90113-6" @default.
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