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- W2000993400 abstract "The anion radical of Mn3(μ-H)3(CO)12 has been generated in frozen 2-methylte- trahydrofuran solutions by γ-irradiation and its ESR spectra have been analyzed. The spectra are consistent with D3h geometry of the anion radical. The unpaired electron is accommodated in an a′2; MO (D3h point group) constructed mainly from the manganese d AO's and with bent σ★ characteristics with respect to the three MnMn bonds. The spin densities on the manganese d AO's and on the hydrogen 1s AO are estimated as 0.21 and −0.03, respectively. The g tensor is explained using an MO diagram constructed from a model of the protonated metal-metal bond for the MnHMn bonds." @default.
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- W2000993400 date "1985-04-01" @default.
- W2000993400 modified "2023-10-16" @default.
- W2000993400 title "An ESR study of a hydrido-bridged trimetal cluster, Mn3(μ-H)3(CO)12−." @default.
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- W2000993400 doi "https://doi.org/10.1016/0022-328x(85)80031-0" @default.
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