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- W2000995403 abstract "The vibrational spectra of the Group IIB dimethylmetals (CH3)2M (M = Zn, Cd, Hg) have been studied for all three phases. The data for the vapours and liquids are consistent with G36 symmetry, which involves free rotation of the methyl groups about the metal—carbon bonds. The splittings observed in the low-temperature spectra of solid Me2Zn and Me2Cd have been interpreted in terms of possible crystal structures. An X-ray diffraction powder pattern taken at 170 K shows that Me2Cd crystallizes in a tegragonal form. Variable low-temperature ( < 150 K) Raman spectroscopy for all three compounds indicates that a barrier to free methyl group rotation is gradually produced as the temperature of the solids is lowered." @default.
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- W2000995403 date "1977-01-01" @default.
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- W2000995403 title "Vibrational spectra of gaseous, liquid and solid dimethylzinc(II), -cadmium(II) and -mercury(II)" @default.
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- W2000995403 doi "https://doi.org/10.1016/0584-8539(77)80069-x" @default.
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