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- W2000998770 abstract "The coordination behavior of chiral binucleating ligands of type 1–4 with various transition metals has been investigated. 1H-NMR Titration experiments with zinc(II) salts gave detailed structural information about the structure of the resulting zinc complexes. Ligand 1 forms an unusual C3-symmetric dinuclear zinc complex [Zn2CIL3] (8a) which was characterized by X-ray crystallography. Treatment of complex 8a with various carboxylic acids resulted in ligand-exchange reactions. With ligand 2, a hydroxo-bridged dinuclear copper complex 15 was synthesized and its structure elucidated by X-ray analysis. Solution studies UV and 1H-NMR spectroscopy of the reaction of ligand 3 with ZnII and NII salts revealed the formation of dimeric species of the type [M2X4L2]. Ligand 4 formed well-defined dinuclear complexes with NiII and CuII salts of which the corresponding NiII complex [Ni2(AcO)2(ClO4)2L] (22a) was characterized by crystal-structure analysis." @default.
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- W2000998770 date "2010-06-22" @default.
- W2000998770 modified "2023-09-25" @default.
- W2000998770 title "ChemInform Abstract: Structure and Properties of Transition-Metal Complexes with Chiral C2-Symmetric Binucleating Ligands." @default.
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- W2000998770 doi "https://doi.org/10.1002/chin.199823127" @default.
- W2000998770 hasPublicationYear "2010" @default.
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