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- W2001009234 abstract "Fourier spectroscopy measurements of 14 703 lines from the B-X band system of I2 are analyzed using centrifugal distortion constants calculated from RKR curves by the perturbation theory method of Hutson [J. Phys. B 14, 851–857 (1981)]. Only vibrational and rotational constants are varied in the least-squares fits, with the centrifugal distortion constants fixed at the calculated values. The fit obtained in the present work is as good as when the centrifugal distortion constants are treated as independent parameters, but the molecular constants obtained are physically more meaningful because the statistical correlation between parameters is reduced. The analysis includes B-state vibrational levels up to v′ = 72, which is bound by only 0.5% of the well depth; the method used for calculating centrifugal distortion constants remains reliable even this close to dissociation. It is found that centrifugal distortion constants up to fifth order make significant contributions to the observed line positions." @default.
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- W2001009234 date "1982-12-01" @default.
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- W2001009234 title "Use of calculated centrifugal distortion constants (Dν, Hν, Lν and Mν) in the analysis of the B ← X system of I2" @default.
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- W2001009234 doi "https://doi.org/10.1016/0022-2852(82)90190-4" @default.
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