FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2001025805> ?p ?o ?g. }

• W2001025805 endingPage "200" @default.
• W2001025805 startingPage "191" @default.
• W2001025805 abstract "The geometric and electronic structure of (para)toluene-XY3+ complexes have been determined by ab initio, gradient optimization methods at the MP2 level of theory in a valence double-zeta + polarization basis set. The Y substituents are CH3, H and Cl, and X is any one of the Group 14 atoms; carbon, silicon, germanium, tin and lead. Comparison is made with a recently reported crystal structure of the toluene-Si(Et)3+ complex and gas phase mass spectrometry reactions of tert-butyl and silynium cations with arenes. The carbenium complexes have an essentially classical four-coordinate ring (ipso) carbon atom. In passing from X = Si to X = Pb the XY3 group moves in tandem with the geminally bound hydrogen atom to a position where the X atom is almost directly above the ipso carbon atom and the hydrogen atom is almost coplanar with the benzene ring. In general, one X-Y bond lies parallel to the long axis of toluene to give approximate Cs symmetry complexes. The toluene-XY3+ binding energies are found to increase from the Sn to the Pb complexes for each Y substituent, indicating a special stabilizing interaction for the lead complexes. The binding energies, geometric structures and charge distribution of the complexes are interpreted in terms of classical σ-bonded and localized π-bonding models." @default.
• W2001025805 created "2016-06-24" @default.
• W2001025805 creator A5035777325 @default.
• W2001025805 date "1996-02-01" @default.
• W2001025805 modified "2023-10-11" @default.
• W2001025805 title "Cation-aromatic bonding in Group 14 organometallics" @default.
• W2001025805 cites W1493039177 @default.
• W2001025805 cites W1603380508 @default.
• W2001025805 cites W1970148666 @default.
• W2001025805 cites W1970589789 @default.
• W2001025805 cites W1970769892 @default.
• W2001025805 cites W1973947045 @default.
• W2001025805 cites W1979303743 @default.
• W2001025805 cites W1982154699 @default.
• W2001025805 cites W1985474281 @default.
• W2001025805 cites W1990302350 @default.
• W2001025805 cites W1990479402 @default.
• W2001025805 cites W1993461592 @default.
• W2001025805 cites W1999233351 @default.
• W2001025805 cites W2017312553 @default.
• W2001025805 cites W2017452494 @default.
• W2001025805 cites W2017528132 @default.
• W2001025805 cites W2022950330 @default.
• W2001025805 cites W2031856796 @default.
• W2001025805 cites W2044100393 @default.
• W2001025805 cites W2049247063 @default.
• W2001025805 cites W2051380736 @default.
• W2001025805 cites W2056031511 @default.
• W2001025805 cites W2058749737 @default.
• W2001025805 cites W2058824352 @default.
• W2001025805 cites W2063592080 @default.
• W2001025805 cites W2071429482 @default.
• W2001025805 cites W2079453990 @default.
• W2001025805 cites W2080796053 @default.
• W2001025805 cites W2081030397 @default.
• W2001025805 cites W2085958374 @default.
• W2001025805 cites W2135261637 @default.
• W2001025805 cites W2148941593 @default.
• W2001025805 cites W2160804650 @default.
• W2001025805 cites W2169574418 @default.
• W2001025805 cites W2952335974 @default.
• W2001025805 cites W3120955088 @default.
• W2001025805 cites W3200865976 @default.
• W2001025805 cites W4248284747 @default.
• W2001025805 doi "https://doi.org/10.1016/0020-1693(95)04866-9" @default.
• W2001025805 hasPublicationYear "1996" @default.
• W2001025805 type Work @default.
• W2001025805 sameAs 2001025805 @default.
• W2001025805 citedByCount "17" @default.
• W2001025805 countsByYear W20010258052023 @default.
• W2001025805 crossrefType "journal-article" @default.
• W2001025805 hasAuthorship W2001025805A5035777325 @default.
• W2001025805 hasConcept C112887158 @default.
• W2001025805 hasConcept C121332964 @default.
• W2001025805 hasConcept C138973236 @default.
• W2001025805 hasConcept C147597530 @default.
• W2001025805 hasConcept C168900304 @default.
• W2001025805 hasConcept C178790620 @default.
• W2001025805 hasConcept C184779094 @default.
• W2001025805 hasConcept C185592680 @default.
• W2001025805 hasConcept C2776640939 @default.
• W2001025805 hasConcept C2777691172 @default.
• W2001025805 hasConcept C2778142098 @default.
• W2001025805 hasConcept C2778689049 @default.
• W2001025805 hasConcept C2780378348 @default.
• W2001025805 hasConcept C2781311116 @default.
• W2001025805 hasConcept C2781442258 @default.
• W2001025805 hasConcept C32909587 @default.
• W2001025805 hasConcept C71240020 @default.
• W2001025805 hasConcept C8010536 @default.
• W2001025805 hasConcept C93282013 @default.
• W2001025805 hasConceptScore W2001025805C112887158 @default.
• W2001025805 hasConceptScore W2001025805C121332964 @default.
• W2001025805 hasConceptScore W2001025805C138973236 @default.
• W2001025805 hasConceptScore W2001025805C147597530 @default.
• W2001025805 hasConceptScore W2001025805C168900304 @default.
• W2001025805 hasConceptScore W2001025805C178790620 @default.
• W2001025805 hasConceptScore W2001025805C184779094 @default.
• W2001025805 hasConceptScore W2001025805C185592680 @default.
• W2001025805 hasConceptScore W2001025805C2776640939 @default.
• W2001025805 hasConceptScore W2001025805C2777691172 @default.
• W2001025805 hasConceptScore W2001025805C2778142098 @default.
• W2001025805 hasConceptScore W2001025805C2778689049 @default.
• W2001025805 hasConceptScore W2001025805C2780378348 @default.
• W2001025805 hasConceptScore W2001025805C2781311116 @default.
• W2001025805 hasConceptScore W2001025805C2781442258 @default.
• W2001025805 hasConceptScore W2001025805C32909587 @default.
• W2001025805 hasConceptScore W2001025805C71240020 @default.
• W2001025805 hasConceptScore W2001025805C8010536 @default.
• W2001025805 hasConceptScore W2001025805C93282013 @default.
• W2001025805 hasIssue "1-2" @default.
• W2001025805 hasLocation W20010258051 @default.
• W2001025805 hasOpenAccess W2001025805 @default.
• W2001025805 hasPrimaryLocation W20010258051 @default.
• W2001025805 hasRelatedWork W1974573029 @default.
• W2001025805 hasRelatedWork W1984949433 @default.
• W2001025805 hasRelatedWork W1996937817 @default.
• W2001025805 hasRelatedWork W2035567885 @default.

• next