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• W2001032005 abstract "Complexation of Ni(II), Co(II) and Zn(II) with the photomerocyanines obtained under steady irradiation of spiroindolinonaphthooxazines containing benzothiazolyl substituent in the naphthooxazine moiety induces a slight hypsochromic shift of its visible absorption band and drastically slows down its thermal bleaching in the dark. As a result, the relaxation time at 20°C ranges from 2 to 42 min, the actual value depending on the metal ion and compound. High ‘colourabilities’ up to 5 × 104 M−1 cm−1 (ɛ = 6 × 104 M−1 cm−1) are calculated from the absorbance values obtained by extrapolation to t = 0 of the room temperature linearly descending kinetic curves ln A/t. Complexation with Ni(II), Co(II) and Zn(II) allows the spiroindolinonaphthooxazines to isomerize to their open-coloured form even under dark conditions giving a complex spectroscopically identical to the photoinduced product and greatly increasing its lifetime to several days." @default.
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• W2001032005 date "2005-04-01" @default.
• W2001032005 modified "2023-09-29" @default.
• W2001032005 title "Effect of complexation on the photochromism of 5′-(benzothiazol-2-yl)spiroindolinonaphthooxazines in polar solvents" @default.
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• W2001032005 doi "https://doi.org/10.1016/j.jphotochem.2004.10.001" @default.
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