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- W2001047244 abstract "2-Thienyldithienophosphinine (3) has been prepared in three steps starting by the ring expansion of dithienophosphole (4) upon reaction with 2-thiophenecarboxylic acid chloride, triethylamine, and water. DFT calculations indicate that the replacement of the phenyl in 2-phenyldithienophosphinine (2) by the 2-thienyl substituent in 3 significantly reduces the HOMO−LUMO gap. Accordingly, 3 reacts cleanly and quantitatively with 2,3-dimethylbutadiene to give the [2+4] cycloadduct 11, whose structure has been confirmed by X-ray crystal structure analysis, whereas 2 reacts slowly and gives the adduct in only 52% yield, and the analogous 2-phenylphosphaphenanthrene (1) gives only an untractable mixture." @default.
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- W2001047244 date "2008-06-26" @default.
- W2001047244 modified "2023-09-23" @default.
- W2001047244 title "The Phosphaalkene-like Reactivity of Dithienophosphinines" @default.
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- W2001047244 doi "https://doi.org/10.1021/om8003256" @default.
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