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• W2001068435 abstract "The current–voltage (I − V) characteristics and the conductance of a molecular wire are evaluated under the condition of a weak electron-vibrational coupling. It is shown that, in the case of strong couplings between the molecular wire and the electrodes, the current formation is associated with a complicated mixture of superexchange (elastic) and sequential (inelastic) transfer processes just within the molecular wire. At a large energy gap between the level positions of the terminal and interior wire units, the transfer along a sequential electronic pathway becomes noneffective. Therefore, the current is mainly determined by an elastic mechanism. If molecule–electrode couplings are weak, the I − V characteristics are connected with the interfacial charge hopping processes limiting the common charge transmission." @default.
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• W2001068435 date "2007-05-21" @default.
• W2001068435 modified "2023-10-16" @default.
• W2001068435 title "Current Assymetry Caused by Molecule–Electrode Contacts" @default.
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• W2001068435 doi "https://doi.org/10.1080/15421400701220999" @default.
• W2001068435 hasPublicationYear "2007" @default.
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