Matches in SemOpenAlex for { <https://semopenalex.org/work/W2001071928> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2001071928 endingPage "535" @default.
- W2001071928 startingPage "527" @default.
- W2001071928 abstract "The excision of polymeric {M3S7X4}x (M=Mo, W; X=Cl, Br) cluster phases with diphosphines (dmpe, dppe) in acetonitrile affords a one step general synthetic route for the preparation of trinuclear molecular clusters with formula [M3S4X3(diphos)3]+ (M=Mo, W; X=Cl, Br and diphos=dmpe, dppe) in high yields. Following this strategy, the cluster cations [Mo3S4Br3(dmpe)3]+ and [W3S4Br3(dppe)3]+ have been prepared for the first time. This last tungsten cluster has proved to be a useful synthon for the synthesis of the hydride derivative [W3S4H3(dppe)3]+ in moderate yields. The crystal structure of [W3S4H3(dppe)3](BPh4) consists of a equilateral tungsten triangle with one capping and three bridging sulfur atoms defining a incomplete W3S4 cuboidal unit in which the tungsten and the sulfur atoms occupy adjacent vertex of a cube with a metal atom missing. The hydride ligand occupies the outer position of the metal in a pseudo-octahedral environment. The other two outer positions on each metal are occupied by the diphosphine phosphorus atoms, located one above and one bellow the M3 plane resulting in two different 31P{1H} NMR signals. Electrochemical studies for all trinuclear clusters reported show one quasi reversible and one irreversible reduction process." @default.
- W2001071928 created "2016-06-24" @default.
- W2001071928 creator A5014034458 @default.
- W2001071928 creator A5038678975 @default.
- W2001071928 creator A5075365520 @default.
- W2001071928 creator A5076496878 @default.
- W2001071928 creator A5076865206 @default.
- W2001071928 date "2001-03-01" @default.
- W2001071928 modified "2023-09-25" @default.
- W2001071928 title "High yield synthesis of trinuclear [M3S4X3(diphos)3]+ (M=Mo, W; X=Cl, Br and diphos=dmpe, dppe) molecular clusters from solid state materials. Synthesis and structure of [W3S4H3(dppe)3](BPh4)" @default.
- W2001071928 cites W1489196146 @default.
- W2001071928 cites W1969669397 @default.
- W2001071928 cites W1975918439 @default.
- W2001071928 cites W1987437543 @default.
- W2001071928 cites W2013860210 @default.
- W2001071928 cites W2029146125 @default.
- W2001071928 cites W2041375903 @default.
- W2001071928 cites W2050531109 @default.
- W2001071928 cites W2051372963 @default.
- W2001071928 cites W2059251698 @default.
- W2001071928 cites W2077573825 @default.
- W2001071928 cites W2081107592 @default.
- W2001071928 cites W2086476950 @default.
- W2001071928 cites W2095370812 @default.
- W2001071928 cites W2516551511 @default.
- W2001071928 cites W2952996500 @default.
- W2001071928 cites W572406511 @default.
- W2001071928 doi "https://doi.org/10.1016/s0277-5387(00)00640-9" @default.
- W2001071928 hasPublicationYear "2001" @default.
- W2001071928 type Work @default.
- W2001071928 sameAs 2001071928 @default.
- W2001071928 citedByCount "51" @default.
- W2001071928 countsByYear W20010719282012 @default.
- W2001071928 countsByYear W20010719282013 @default.
- W2001071928 countsByYear W20010719282014 @default.
- W2001071928 countsByYear W20010719282015 @default.
- W2001071928 countsByYear W20010719282016 @default.
- W2001071928 countsByYear W20010719282017 @default.
- W2001071928 countsByYear W20010719282018 @default.
- W2001071928 countsByYear W20010719282019 @default.
- W2001071928 countsByYear W20010719282021 @default.
- W2001071928 crossrefType "journal-article" @default.
- W2001071928 hasAuthorship W2001071928A5014034458 @default.
- W2001071928 hasAuthorship W2001071928A5038678975 @default.
- W2001071928 hasAuthorship W2001071928A5075365520 @default.
- W2001071928 hasAuthorship W2001071928A5076496878 @default.
- W2001071928 hasAuthorship W2001071928A5076865206 @default.
- W2001071928 hasConcept C115624301 @default.
- W2001071928 hasConcept C116569031 @default.
- W2001071928 hasConcept C164866538 @default.
- W2001071928 hasConcept C170493617 @default.
- W2001071928 hasConcept C178790620 @default.
- W2001071928 hasConcept C185592680 @default.
- W2001071928 hasConcept C198819137 @default.
- W2001071928 hasConcept C199360897 @default.
- W2001071928 hasConcept C2777961443 @default.
- W2001071928 hasConcept C40869318 @default.
- W2001071928 hasConcept C41008148 @default.
- W2001071928 hasConcept C544153396 @default.
- W2001071928 hasConcept C55493867 @default.
- W2001071928 hasConcept C71240020 @default.
- W2001071928 hasConcept C8010536 @default.
- W2001071928 hasConceptScore W2001071928C115624301 @default.
- W2001071928 hasConceptScore W2001071928C116569031 @default.
- W2001071928 hasConceptScore W2001071928C164866538 @default.
- W2001071928 hasConceptScore W2001071928C170493617 @default.
- W2001071928 hasConceptScore W2001071928C178790620 @default.
- W2001071928 hasConceptScore W2001071928C185592680 @default.
- W2001071928 hasConceptScore W2001071928C198819137 @default.
- W2001071928 hasConceptScore W2001071928C199360897 @default.
- W2001071928 hasConceptScore W2001071928C2777961443 @default.
- W2001071928 hasConceptScore W2001071928C40869318 @default.
- W2001071928 hasConceptScore W2001071928C41008148 @default.
- W2001071928 hasConceptScore W2001071928C544153396 @default.
- W2001071928 hasConceptScore W2001071928C55493867 @default.
- W2001071928 hasConceptScore W2001071928C71240020 @default.
- W2001071928 hasConceptScore W2001071928C8010536 @default.
- W2001071928 hasIssue "6" @default.
- W2001071928 hasLocation W20010719281 @default.
- W2001071928 hasOpenAccess W2001071928 @default.
- W2001071928 hasPrimaryLocation W20010719281 @default.
- W2001071928 hasRelatedWork W167857991 @default.
- W2001071928 hasRelatedWork W1969215021 @default.
- W2001071928 hasRelatedWork W1969352129 @default.
- W2001071928 hasRelatedWork W1973253274 @default.
- W2001071928 hasRelatedWork W2009654379 @default.
- W2001071928 hasRelatedWork W2039836026 @default.
- W2001071928 hasRelatedWork W2074779033 @default.
- W2001071928 hasRelatedWork W2316937681 @default.
- W2001071928 hasRelatedWork W2324887520 @default.
- W2001071928 hasRelatedWork W2950083354 @default.
- W2001071928 hasVolume "20" @default.
- W2001071928 isParatext "false" @default.
- W2001071928 isRetracted "false" @default.
- W2001071928 magId "2001071928" @default.
- W2001071928 workType "article" @default.