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- W2001075843 abstract "The antiferromagnetic phase transition of an organic free radical, 1,3-bisdiphenylene-2- (p-chlorophenyl) -allyl, was confirmed by the antiferromagnetic resonance (AFMR). The long range ordered state of the unpaired electron spins was elucidated in detail. The AFMR absorptions were obtained in polycrystalline specimen using a conventional X-band spectrometer. The AFMR theory of a two-sublattice model with an orthorhombic anisotropy was applied to the results obtained. The antiferromagnetic resonance parameters C1 and C2 were determined to be 2.25×106 and 7.84×106 (Oe2) at the absolute zero of temperature, respectively. The degree of an orthorhombic anisotropy was thus determined to be C2/C1=3.5. Assuming the exchange field, which was moderately estimated in terms of the exchange parameters obtained from susceptibility measurements, the anisotropy field amounts to be 17 Oe. The antiferromagnetic spin flop field Hc was also determined to be 1500 Oe at the absolute zero of temperature. Both of the anisotropy and the spin flop fields are in excellent agreement with those obtained from torque measurements. It is clarified that a reliable determination of the parameters in the antiferromagnetic state is possible from polycrystalline samples of organic free radicals." @default.
- W2001075843 created "2016-06-24" @default.
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- W2001075843 date "1977-09-15" @default.
- W2001075843 modified "2023-09-27" @default.
- W2001075843 title "Antiferromagnetic resonance of organic free radical, polycrystalline 1,3-bisdiphenylene-2- (<i>p</i>-chlorophenyl) -allyl" @default.
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- W2001075843 doi "https://doi.org/10.1063/1.435151" @default.
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