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- W2001091519 abstract "Abstract The capability of bis(trimethylsilyl)amidoalane to act as a hydride transfer reagent in organolanthanide chemistry was investigated by probing its reactivity toward alkylyttrium complexes. Reaction with Cp* 2 YMe(thf) led to the isolation of the bimetallic complex Cp* 2 Y(μ‐H) 2 Al(Me)[N(SiMe 3 ) 2 ] (Cp* = 1,2,3,4,5‐pentamethylcyclopentadiene), whereas reaction with [Cp*YMe 2 ] 3 gave MeAl[N(SiMe 3 ) 2 ] 2 as the only isolable hydride transfer product. The dimeric complex [Cp*Y{N(SiMe 3 ) 2 }(μ‐H)] 2 represents one possible product of the aforementioned reaction that could be structurally characterized. The use of [YMe 3 ] n as the alkylyttrium source led to the isolation of Y[N(SiMe 3 ) 2 ] 3 , which displays competition between amide and hydride transfer. Finally, the performance of Cp* 2 Y(μ‐H) 2 Al(Me)[N(SiMe 3 ) 2 ] and [YMe 3 ] n in the hydroalumination of 1‐octene was tested, and these compounds represent the first rare‐earth metal catalysts for this transformation." @default.
- W2001091519 created "2016-06-24" @default.
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- W2001091519 creator A5027179478 @default.
- W2001091519 date "2013-05-17" @default.
- W2001091519 modified "2023-10-17" @default.
- W2001091519 title "Rare‐Earth‐Metal‐Promoted Hydroalumination" @default.
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- W2001091519 doi "https://doi.org/10.1002/ejic.201300504" @default.
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