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- W2001111501 abstract "The effect of ring strain in molecules of C 5 -C 8 cycloalkenes and that of electronegativity of the attacking radicals upon reactivity of cycloalkenes in 1,2 addition reactions was studied by using a simple perturbation approach. The trends of the experimentally determined reactivities of cycloalkenes towards CH 3 , CCl 3 , CF 2 CF 2 CF 3 , CH 3 CO, NCCHCO 2 H 5 , C 2 H 5 , C 2 H 5 S and Br radicals were found to be in an acceptable agreement with the trends of the calculated Fukui's delocalisabilities D r . The reactivity of cycloalkenes appears to be influenced by I-strain in the cycloalkene molecules as well as by electronegativity of the attacking radicals." @default.
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- W2001111501 date "1981-01-01" @default.
- W2001111501 modified "2023-09-25" @default.
- W2001111501 title "PMO-treatment of the structure-reactivity relationships in free radical addition reactions of cycloalkenes" @default.
- W2001111501 doi "https://doi.org/10.1135/cccc19812524" @default.
- W2001111501 hasPublicationYear "1981" @default.
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