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• W2001126345 abstract "The intrinsic reaction rates for the hydriding and dehydriding of LaNi5 were determined over a wide range of pressures in the temperature range 60–65 °C. Approximately isothermal conditions were maintained by a new thermal ballast technique. The reaction rates measured are faster than those determined previously because previous measurements were heat flow limited. The data analysis takes into account the simultaneous operation in series of surface, diffusion and α-β interface intrinsic processes. It is concluded that the hydriding rate is under the mixed control of a surface process with an activation energy QS/R of 1100 K and a bulk process with an activation energy QB/R of 5480 K, a value similar to that for diffusion. The bulk process tends to become rate limiting at low temperatures and at high pressures. Dehydriding appears to be rate limited by a surface process with QS/R = 0 K." @default.
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• W2001126345 date "1983-01-01" @default.
• W2001126345 modified "2023-10-14" @default.
• W2001126345 title "Hydriding and dehydriding rates of the LaNi5-H system" @default.
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• W2001126345 doi "https://doi.org/10.1016/0022-5088(83)90255-2" @default.
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