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- W2001128805 abstract "MMe5(dmpe) (M = Nb or Ta, dmpe = Me2PCH2CH2PMe2) reacts with H2 (500 atm) and dmpe in THF at 60°C to give MH5(dmpe)2− NbH5(dmpe)2 readily reacts with two mol of CO or ethylene (L) to give NbHL2(dmpe)2. The exchange of the hydride ligand with the ethylene protons in NbH(C2H4)2(dmpe)2 is not rapid on the 1H NMR time scale (60 MHz) at 95°C." @default.
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- W2001128805 date "1976-11-01" @default.
- W2001128805 modified "2023-09-23" @default.
- W2001128805 title "The preparation of NbH5(Me2PCH2CH2Me2)2 and NbHL2(Me2PCH2CH2PMe2)2 (L = CO or C2H4)" @default.
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- W2001128805 doi "https://doi.org/10.1016/s0022-328x(00)85091-3" @default.
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