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• W2001140347 abstract "Abstract The interactions of transition metal tetrafluoroborates with 2,6-lutidine N-oxide(L) in organic solvents were studied, under various conditions. A number of adducts of the types [CrL 6 ](BF 4 ) 3 , [ML 4 ](BF 4 ) 2 (M = Fe, Cu, Zn, Cd), [CoL 4 (FBF 3 )](BF 4 )·H 2 O and [L 3 NiL 2 NiL 3 ](BF 4 ) 4 were isolated and characterized. In most cases, these compounds are similar to the corresponding metal perchlorate complexes (including the square-planar Fe 2+ complex, which is partially spin-paired (S = 1; μ eff = 3.55 μB)). The only differences are that the new Co 2+ complex involves coordinated FBF 3 , while the 4:1 Co(ClO 4 ) 2 analog contains exclusively ionic ClO 4 , and that, whereas the diamagnetic, square-planar [NiL 4 ] (ClO 4 2 complex remains unchanged for a long time before dimerizing to the paramagnetic [L 3 NiL 2 NiL 3 ](ClO 4 ) 4 , with the [NiL 4 ](BF 4 ) 2 analog the monomeric species is unstable, dimerizing within a few hours. These differences were attributed to the significantly smaller steric hindrance exerted by BF 4 relative to ClO 4 . In addition to the preceding adducts, a number of products of the types [L 3 CoF 2 CoL 3 ] (BF 4 ) 2 , [(F 2 BF 2 )L(ROH)MF 2 M(ROH)L(F 2 BF 2 )] (R = CH 3 for M = Mn; R = C 2 H 5 for M = Ni) and MnLF(BF 4 )·4MnF 2 were isolated. Formation of MF(BF 4 ) or MF 2 is accompanied by elimination of BF 3 ·L from the initially formed adducts. This reaction seems to be favored when the initial adducts of L with M(BF 4 ) 2 involves coordinated tetrafluoroborato ligands [1]." @default.
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• W2001140347 date "1980-01-01" @default.
• W2001140347 modified "2023-10-14" @default.
• W2001140347 title "Transition metal tetrafluoroborate interactions with 2,6-lutidine N-oxide" @default.
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• W2001140347 doi "https://doi.org/10.1016/s0020-1693(00)93648-x" @default.
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