FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2001144507> ?p ?o ?g. }

• W2001144507 endingPage "1559" @default.
• W2001144507 startingPage "1553" @default.
• W2001144507 abstract "We describe a white emitting coordination network solid that can be conveniently applied as a thin film onto a commercial UV-LED lamp for practical white lighting applications. The solid state material was discovered in an exercise of exploring molecular building blocks equipped with secondary groups for fine-tuning the structures and properties of coordination nets. Specifically, CH3SCH2CH2S- and (S)-CH3(OH)CHCH2S- (2-hydroxylpropyl) were each attached as secondary groups to the 2,5- positions of 1,4-benzenedicarboxylic acid (bdc), and the resultant molecules (L1 and L2, respectively) were crystallized with Pb(II) into the topologically similar 3D nets of PbL1 and PbL2, both consisting of interlinked Pb-carboxyl chains. While the CH3S- groups in PbL1 are not bonded to the Pb(II) centers, the hydroxy groups in PbL2 participate in coordinating to Pb(II) and thus modify the bonding features around the Pb(II), but only to a slight and subtle degree (e.g., Pb–O distances 2.941–3.116 Å). Interestingly, the subtle change in structure significantly impacts the properties, i.e., while the photoluminescence of PbL1 is yellowish green, PbL2 features bright white emission. Also, the homochiral side group in PbL2 imparts significant second harmonic generation, in spite of its seemingly weak association with the main framework (the NLO-phore). In a broad perspective, this work showcases the idea of secondary group participation (SGP) in the construction of coordination networks, an idea that parallels that of hemilabile ligands in organometallics and points to an effective strategy in developing advanced functions in solid state framework materials." @default.
• W2001144507 created "2016-06-24" @default.
• W2001144507 creator A5025944326 @default.
• W2001144507 creator A5070735149 @default.
• W2001144507 creator A5076919169 @default.
• W2001144507 creator A5084113038 @default.
• W2001144507 date "2012-01-10" @default.
• W2001144507 modified "2023-09-28" @default.
• W2001144507 title "White Light Emission and Second Harmonic Generation from Secondary Group Participation (SGP) in a Coordination Network" @default.
• W2001144507 cites W1628423641 @default.
• W2001144507 cites W1964398385 @default.
• W2001144507 cites W1964676341 @default.
• W2001144507 cites W1968954504 @default.
• W2001144507 cites W1970778211 @default.
• W2001144507 cites W1975780653 @default.
• W2001144507 cites W1976536874 @default.
• W2001144507 cites W1976765548 @default.
• W2001144507 cites W1976801046 @default.
• W2001144507 cites W1977761176 @default.
• W2001144507 cites W1979400492 @default.
• W2001144507 cites W1981890562 @default.
• W2001144507 cites W1981970530 @default.
• W2001144507 cites W1982093746 @default.
• W2001144507 cites W1984851754 @default.
• W2001144507 cites W1988624386 @default.
• W2001144507 cites W1992555844 @default.
• W2001144507 cites W1995644115 @default.
• W2001144507 cites W1996375806 @default.
• W2001144507 cites W1997410309 @default.
• W2001144507 cites W2000187033 @default.
• W2001144507 cites W2000195059 @default.
• W2001144507 cites W2001655788 @default.
• W2001144507 cites W2002018099 @default.
• W2001144507 cites W2003183256 @default.
• W2001144507 cites W2004627020 @default.
• W2001144507 cites W2005331110 @default.
• W2001144507 cites W2005877813 @default.
• W2001144507 cites W2005960784 @default.
• W2001144507 cites W2006753411 @default.
• W2001144507 cites W2008136988 @default.
• W2001144507 cites W2008653811 @default.
• W2001144507 cites W2009626516 @default.
• W2001144507 cites W2014659473 @default.
• W2001144507 cites W2015347930 @default.
• W2001144507 cites W2016808561 @default.
• W2001144507 cites W2020353271 @default.
• W2001144507 cites W2022167379 @default.
• W2001144507 cites W2022949493 @default.
• W2001144507 cites W2023957345 @default.
• W2001144507 cites W2028821162 @default.
• W2001144507 cites W2031709208 @default.
• W2001144507 cites W2031840601 @default.
• W2001144507 cites W2033369587 @default.
• W2001144507 cites W2035460169 @default.
• W2001144507 cites W2035952367 @default.
• W2001144507 cites W2041893040 @default.
• W2001144507 cites W2043136052 @default.
• W2001144507 cites W2043666214 @default.
• W2001144507 cites W2050172973 @default.
• W2001144507 cites W2051191132 @default.
• W2001144507 cites W2051583102 @default.
• W2001144507 cites W2055949694 @default.
• W2001144507 cites W2056890421 @default.
• W2001144507 cites W2059858109 @default.
• W2001144507 cites W2060487974 @default.
• W2001144507 cites W2061874943 @default.
• W2001144507 cites W2063216708 @default.
• W2001144507 cites W2063459172 @default.
• W2001144507 cites W2067463371 @default.
• W2001144507 cites W2071164296 @default.
• W2001144507 cites W2075756164 @default.
• W2001144507 cites W2075984986 @default.
• W2001144507 cites W2076087758 @default.
• W2001144507 cites W2077612856 @default.
• W2001144507 cites W2078444809 @default.
• W2001144507 cites W2084852727 @default.
• W2001144507 cites W2085142740 @default.
• W2001144507 cites W2090264019 @default.
• W2001144507 cites W2090748133 @default.
• W2001144507 cites W2091020521 @default.
• W2001144507 cites W2091376230 @default.
• W2001144507 cites W2094822386 @default.
• W2001144507 cites W2095394033 @default.
• W2001144507 cites W2095915347 @default.
• W2001144507 cites W2096867388 @default.
• W2001144507 cites W2101000826 @default.
• W2001144507 cites W2102657089 @default.
• W2001144507 cites W2106557187 @default.
• W2001144507 cites W2108705076 @default.
• W2001144507 cites W2110149049 @default.
• W2001144507 cites W2117072882 @default.
• W2001144507 cites W2118742600 @default.
• W2001144507 cites W2119659749 @default.
• W2001144507 cites W2121904540 @default.
• W2001144507 cites W2143234901 @default.
• W2001144507 cites W2145238250 @default.
• W2001144507 cites W2147252225 @default.
• W2001144507 cites W2152932169 @default.

• next