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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2001145375> ?p ?o ?g. }

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• W2001145375 abstract "A concise second-generation total synthesis of the fungal-derived alkaloid (+)-gliocladin C (11) in 10 steps and 11% overall yield from isatin is reported. In addition, the epipolythiodioxopiperazine (ETP) natural product (+)-gliocladine C (6) has been prepared in six steps and 29% yield from the di-(tert-butoxycarbonyl) precursor of 11. The total synthesis of 6 constitutes the first total synthesis of an ETP natural product containing a hydroxyl substituent adjacent to a quaternary carbon stereocenter in the pyrrolidine ring." @default.
• W2001145375 created "2016-06-24" @default.
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• W2001145375 date "2011-04-07" @default.
• W2001145375 modified "2023-09-27" @default.
• W2001145375 title "Enantioselective Total Synthesis of (+)-Gliocladine C: Convergent Construction of Cyclotryptamine-Fused Polyoxopiperazines and a General Approach for Preparing Epidithiodioxopiperazines from Trioxopiperazine Precursors" @default.
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• W2001145375 doi "https://doi.org/10.1021/ja201789v" @default.
• W2001145375 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3090078" @default.
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